tin monoxide
- Formula: OSn
- Molecular weight: 134.709
- IUPAC Standard InChI: InChI=1S/O.Sn
- IUPAC Standard InChIKey: QHGNHLZPVBIIPX-UHFFFAOYSA-N
- CAS Registry Number: 21651-19-4
- Chemical structure:
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Condensed phase thermochemistry data
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -67.091 ± 0.048 | kcal/mol | Review | Cox, Wagman, et al., 1984 | tetragonal phase; CODATA Review value |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid,1 bar | 13.66 ± 0.072 | cal/mol*K | Review | Cox, Wagman, et al., 1984 | tetragonal phase; CODATA Review value |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.5980 ± 0.0060 | LPES | Davico, Ramond, et al., 2000 | B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.9 ± 0.2 | EI | Makarov and Zbezhneva, 1993 | LL |
| 9.60 ± 0.02 | PE | Dyke, Morris, et al., 1982 | LBLHLM |
| 10.4 ± 0.3 | EI | Lau, Brittain, et al., 1981 | LLK |
| 10. ± 1. | EI | Drowart, Myers, et al., 1972 | LLK |
| 10.5 ± 0.5 | EI | Colin, Drowart, et al., 1965 | RDSH |
| 9.98 | PE | Dyke, Morris, et al., 1982 | Vertical value; LBLHLM |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Sn+ | 13. | O | EI | Colin, Drowart, et al., 1965 | RDSH |
Constants of diatomic molecules
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through September, 1977
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Unidentified absorption bands, 64920 - 68360 cm-1. | ||||||||||||
| ↳Barrow and Rowlinson, 1954 | ||||||||||||
| G | 58806 1 | 724 H | 21 | G ← X R | 58752 H | |||||||
| ↳missing citation | ||||||||||||
| F | (57669) | [466] H | F ← X R | 57492 H | ||||||||
| ↳missing citation | ||||||||||||
| Unidentified absorption bands, 53250 - 57670 cm-1. | ||||||||||||
| ↳Barrow and Rowlinson, 1954 | ||||||||||||
| Absorption continuum between 51630 and 51920 cm-1. | ||||||||||||
| ↳Barrow and Rowlinson, 1954 | ||||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| E | 36295 | 508.0 H | 2.9 2 | E ↔ X R | 36138 H | |||||||
| ↳Loomis and Watson, 1934; missing citation | ||||||||||||
| D 1Π | 29624 | [573.6] Z | 3.08 | -0.135 | 0.31455 3 4 | 0.0025 | 4.0E-7 | 1.9487 | D ↔ X 5 6 R | 29503.2 Z | ||
| ↳missing citation; Jevons, 1938; missing citation | ||||||||||||
| A large number of emission bands in the visible and near UV region has been observed by various methods Mahanti, 1931, Joshi and Yamdagini, 1967, Smith and Meyer, 1968. A satisfactory interpretation is still lacking. | ||||||||||||
| B (1) | (24890) | [560] | [1.992] | B ← X R | 24760 | |||||||
| ↳Deutsch and Barrow, 1964 | ||||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| A (0+) | (24333) | [555] | [0.2964] | [2.008] | A ← X R | 24200 | ||||||
| ↳Deutsch and Barrow, 1964 | ||||||||||||
| X 1Σ+ | 0 | [814.6] Z | 3.73 H | 0.3557191 4 | 0.0021429 | -7E-7 | (2.66E-7) | 1.832505 7 | ||||
| ↳Ogden and Ricks, 1970 | ||||||||||||
| Microwave sp. 8 | ||||||||||||
| ↳Torring, 1967 | ||||||||||||
Notes
| 1 | Barrow and Rowlinson, 1954 give 58809.6 which does not fit with their observed (or calculated) ν00. |
| 2 | ωexe = 2.9 - 5E-5(v+1/2)5 (valid for v' ≤ 17). |
| 3 | Small Λ-type doubling. Several perturbations, probably by a 1Π (or 1Δ) state Lagerqvist, Nilsson, et al., 1959. |
| 4 | RKR potential functions Nair, Singh, et al., 1965. |
| 5 | Franck-Condon factors, relative band intensities, variation of electronic transition moment with r Dube and Rai, 1971. |
| 6 | The observed 118Sn and 116Sn isotope shifts for the 0-1 band Lagerqvist, Nilsson, et al., 1959 seem to confirm the v' numbering. See, however, Smith and Meyer, 1968 who suggest that v' be increased by 1. |
| 7 | IR Spectrum 11 |
| 8 | Torring, 1967 gives rotational constants for seven isotopes. Dipole moment from Stark effect of rotation spectrum μel(v=0) = 4.32 D Mahanti, 1931. Zeeman effect Honerjager and Tischer, 1973, gJ(v=0) = -0.1463. |
| 9 | Thermochemical value Colin, Drowart, et al., 1965. Extrapolation of the E-X v"=0 progression gives a dissociation limit at 45770 cm-1 Barrow and Rowlinson, 1954; if it corresponds to 3P1 + 3P1 [see Barrow, 1970] a dissociation energy of 5.45 eV would follow. |
| 10 | Both v=1 and v=2 are extensively perturbed. |
| 11 | In argon and nitrogen matrices. |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Davico, Ramond, et al., 2000
Davico, G.E.; Ramond, T.M.; Lineberger, W.C.,
Photoelectron Spectroscopy of SnO-,
J. Chem. Phys., 2000, 113, 19, 8852, https://doi.org/10.1063/1.1318194
. [all data]
Makarov and Zbezhneva, 1993
Makarov, A.V.; Zbezhneva, S.G.,
Use of high-temperature mass spectrometry for analysis of the vapour phase of some substances used in film deposition,
Vysokochist. Veshchestva, 1993, 1, 124. [all data]
Dyke, Morris, et al., 1982
Dyke, J.M.; Morris, A.; Ridha, A.M.A.; Snijders, J.G.,
Gas phase high temperature photoelectron spectroscopy: The tin monoxide molecule,
Chem. Phys., 1982, 67, 245. [all data]
Lau, Brittain, et al., 1981
Lau, K.H.; Brittain, R.D.; Hildenbrand, D.L.,
The dissociation energy of AsO from gaseous equilibrium measurements,
Chem. Phys. Lett., 1981, 81, 227. [all data]
Drowart, Myers, et al., 1972
Drowart, J.; Myers, C.E.; Szwarc, R.; Vander Auwera-Mahieu, A.; Uy, O.M.,
Determination by the mass spectrometric Knudsen cell method of the atomization energies of the molecules PO and PO2,
J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1749. [all data]
Colin, Drowart, et al., 1965
Colin, R.; Drowart, J.; Verhaegen, G.,
Mass spectrometric study of the vaporization of tin oxides. Dissociation energy of SnO,
J. Chem. Soc. Faraday Trans., 1965, 61, 1364. [all data]
Barrow and Rowlinson, 1954
Barrow, R.F.; Rowlinson, H.C.,
The absorption spectra of the gaseous monoxides of silicon, germanium and tin in the Schumann region,
Proc. Roy. Soc. (London), 1954, A224, 374. [all data]
Loomis and Watson, 1934
Loomis, F.W.; Watson, T.F.,
A new band system of tin oxide,
Phys. Rev., 1934, 45, 805. [all data]
Jevons, 1938
Jevons, W.,
A note on the near ultra-violet band system of SnO,
Proc. Phys. Soc. London, 1938, 50, 910. [all data]
Mahanti, 1931
Mahanti, P.C.,
Die bandenspektren von zinnoxyd. Teil I. Die schwingungsanalyse der blau=violett=banden,
Z. Phys., 1931, 68, 114. [all data]
Joshi and Yamdagini, 1967
Joshi, M.M.; Yamdagini, R.,
Flame emission spectrum of SnO molecule in the visible region,
Indian J. Phys., 1967, 41, 275. [all data]
Smith and Meyer, 1968
Smith, J.J.; Meyer, B.,
The absorption and fluorescence spectrum of SnS and SnO: matrix-induced intersystem crossing,
J. Mol. Spectrosc., 1968, 27, 304. [all data]
Deutsch and Barrow, 1964
Deutsch, E.W.; Barrow, R.F.,
Rotational analysis of bands of the 3Π-X1Σ+ system of stannous oxide,
Nature (London), 1964, 201, 815. [all data]
Ogden and Ricks, 1970
Ogden, J.S.; Ricks, M.J.,
Matrix isolation studies of group IV oxides. III. Infrared spectra and structures of SnO, Sn2O2, Sn3O3, and Sn4O4,
J. Chem. Phys., 1970, 53, 896. [all data]
Torring, 1967
Torring, T.,
Das Mikrowellenrotationsspektrum des SnO,
Z. Naturforsch. A, 1967, 22, 1234. [all data]
Lagerqvist, Nilsson, et al., 1959
Lagerqvist, A.; Nilsson, N.E.L.; Wigartz, K.,
Rotational analysis of the A1Π-X1Σ system of SnO,
Ark. Fys., 1959, 15, 521. [all data]
Nair, Singh, et al., 1965
Nair, K.P.R.; Singh, R.B.; Rai, D.K.,
Potential-energy curves and dissociation energies of oxides and sulfides of group IV A elements,
J. Chem. Phys., 1965, 43, 3570. [all data]
Dube and Rai, 1971
Dube, P.S.; Rai, D.K.,
Electronic transition moment variation in D1Π-X1Σ system of SnO molecule and determination of the effective vibrational temperature,
J. Phys. B:, 1971, 4, 579. [all data]
Honerjager and Tischer, 1973
Honerjager, R.; Tischer, R.,
gJ-Faktor der Molekeln SnO und PbO und Anisotropie ihrer magnetischen Suszeptibilitat,
Z. Naturforsch. A, 1973, 28, 1372. [all data]
Barrow, 1970
Barrow,
In Rosen, 1970, 1970, 323. [all data]
Rosen, 1970
Rosen, B.,
International tables of selected constants. 17. Spectroscopic data relative to diatomic molecules, Pub. Pergamon Press, Oxford, 1970, 0. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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