Mononitrogen monosulfide

• Formula: NS
• Molecular weight: 46.072
• IUPAC Standard InChI: InChI=1S/NS/c1-2 Copy

  
• IUPAC Standard InChIKey: QXTCFDCJXWLNAP-UHFFFAOYSA-N Copy
• CAS Registry Number: 12033-56-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Gas phase ion energetics data
  • Constants of diatomic molecules
  • References
  • Notes
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • Gas Phase Kinetics Database
• Options:
  • Switch to SI units

Gas phase thermochemistry data

Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to NS⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Constants of diatomic molecules

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through May, 1977

Notes

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Burnett, Feigerle, et al., 1982
Burnett, S.M.; Feigerle, C.S.; Stevens, A.E.; Lineberger, C.W., Photoelectron spectroscopy of CS- and NS-, J. Phys. Chem., 1982, 86, 4486. [all data]

O'Hare, 1970
O'Hare, P.A.G., Dissociation energies, enthalpies of formation, ionization potentials, and dipole moments of NS and NS⁺, J. Chem. Phys., 1970, 52, 2992. [all data]

Dyke, Morris, et al., 1977
Dyke, J.M.; Morris, A.; Trickle, I.R., Characterization of the ground ionic state of the NS molecule using photoelectron spectroscopy, J. Chem. Soc. Faraday Trans. 2, 1977, 73, 147. [all data]

Bialski and Grein, 1976
Bialski, M.; Grein, F., Theoretical studies on low-lying valence states of NS, SiF, and CCl, J. Mol. Spectrosc., 1976, 61, 321. [all data]

Joshi, 1966
Joshi, K.C., The emission spectrum of the NS molecule, Z. Phys., 1966, 191, 126. [all data]

Vervloet and Jenouvrier, 1976
Vervloet, M.; Jenouvrier, A., Etats Rydberg de NS. Etude du domaine spectral 2400-1750 Å, Can. J. Phys., 1976, 54, 1909. [all data]

Narasimham and Subramanian, 1969
Narasimham, N.A.; Subramanian, T.K.B., Isotope shift studies in the spectra of NS and PS, J. Mol. Spectrosc., 1969, 29, 294. [all data]

Jenouvrier and Pascat, 1973
Jenouvrier, A.; Pascat, B., Etats de valence de NS dans le domaine 2250-3800 Å, Can. J. Phys., 1973, 51, 2143. [all data]

Fowler and Bakker, 1932
Fowler, A.; Bakker, C.J., The band spectrum of nitrogen sulphide (NS), Proc. R. Soc. London A, 1932, 136, 28. [all data]

Barrow, Downie, et al., 1952
Barrow, R.F.; Downie, A.R.; Laird, R.K., The spectrum of NS, Proc. Phys. Soc. London Sect. A, 1952, 65, 70. [all data]

Barrow, Drummond, et al., 1954
Barrow, R.F.; Drummond, G.; Zeeman, P.B., Rotational analysis of the β band system of the NS molecule, Proc. Phys. Soc. London Sect. A, 1954, 67, 365. [all data]

Narasimham, Raghuveer, et al., 1975
Narasimham, N.A.; Raghuveer, K.; Balasubramanian, T.K., A new electronic transition in NS, J. Mol. Spectrosc., 1975, 54, 160. [all data]

Jenouvrier and Daumont, 1976
Jenouvrier, A.; Daumont, D., The B'²Σ⁺ state of NS, J. Mol. Spectrosc., 1976, 61, 313. [all data]

Narasimham and Srikameswaran, 1963
Narasimham, N.A.; Srikameswaran, K., A new ²Π-X²Π band system of nitrogen sulphide, Nature (London), 1963, 197, 370. [all data]

Smith and Meyer, 1964
Smith, J.J.; Meyer, B., Characterization of the B²Π state of NS in the emission from active nitrogen-sulfur flames, J. Mol. Spectrosc., 1964, 14, 160. [all data]

Goudmand and Dessaux, 1967
Goudmand, P.; Dessaux, O., Formation de molecules NS et NSe electroniquement excitees dans les reactions de l'azote actif sur les chlorures de soufre et de selenium, J. Chim. Phys. Phys.-Chim. Biol., 1967, 64, 135. [all data]

Vidal, Dessaux, et al., 1969
Vidal, B.; Dessaux, O.; Marteel, J.-P.; Goudmand, P., Sur l'emission de nouvelles bandes du systeme B²Π - X²Π de NS dans des reactions chimiluminescentes, C.R. Acad. Sci. Paris, Ser. C, 1969, 268, 2140. [all data]

Amano, Saito, et al., 1969
Amano, T.; Saito, S.; Hirota, E.; Morino, Y., Hyperfine interactions and λ-type doubling in the microwave spectrum of the NS radical, J. Mol. Spectrosc., 1969, 32, 97. [all data]

Carrington and Levy, 1966
Carrington, A.; Levy, D.H., Electron resonance studies of free radicals in the gas phase. Detection of ClO, BrO, and NS, J. Chem. Phys., 1966, 44, 1298. [all data]

Carrington, Howard, et al., 1968
Carrington, A.; Howard, B.J.; Levy, D.H.; Robertson, J.C., Gas phase electron resonance spectrum of NS, Mol. Phys., 1968, 15, 187. [all data]

Uehara and Morino, 1969
Uehara, H.; Morino, Y., Molecular structure of the NS free radical by gas-phase electron paramagnetic resonance, Mol. Phys., 1969, 17, 239. [all data]

Balasubramanian and Narasimham, 1974
Balasubramanian, T.K.; Narasimham, N.A., Reinvestigation of the β and the γ band systems of NS, J. Mol. Spectrosc., 1974, 53, 128. [all data]

Silvers and Chiu, 1974
Silvers, S.J.; Chiu, C.-L., Fluorescence and zero-field level crossing spectroscopy of the C²Σ⁺ state of NS, J. Chem. Phys., 1974, 61, 1475. [all data]

Donovan and Breckenridge, 1971
Donovan, R.J.; Breckenridge, W.H., Reaction of S(3¹D₂) with N₂O, Chem. Phys. Lett., 1971, 11, 520. [all data]

Narasimham and Srikameswaran, 1963, 2
Narasimham, N.A.; Srikameswaran, K., The β- and γ-band systems of ¹⁴NS and ¹⁵NS, Proc. Indian Acad. Sci. Sect. A, 1963, 56, 316. [all data]

Zeeman, 1951
Zeeman, P.B., Rotational analysis of the γ band system of the NS molecule, Can. J. Phys., 1951, 29, 174. [all data]

Byfleet, Carrington, et al., 1971
Byfleet, C.R.; Carrington, A.; Russell, D.K., Electric dipole moments of open-shell diatomic molecules, Mol. Phys., 1971, 20, 271. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, References

• Symbols used in this document:
  

  EA	Electron affinity
  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.