S3 anion
- Formula: S3-
- Molecular weight: 96.196
- CAS Registry Number: 12597-04-5
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -57.3 ± 4.6 | kJ/mol | R-EA | Nimlos and Ellison, 1986 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (S3- • 4294967295S) + S = S3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 302. ± 22. | kJ/mol | N/A | Nimlos and Ellison, 1986 | gas phase |
Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 17000 ± 110 | gas | Nimlos and Ellison, 1986 | |||||
Hunsicker, Jones, et al., 1995 | |||||||
State: D
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 16152 ± 50 | Ne | D-X | 537 | 619 | Shnitko, Fulara, et al., 2008 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | Sym. stretch | 446 | Ne | AB | Shnitko, Fulara, et al., 2008 | |
2 | Bend | 177 | Ne | AB | Shnitko, Fulara, et al., 2008 | ||
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 14259 ± 40 | Ne | C-X | 598 | 701 | Shnitko, Fulara, et al., 2008 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | Sym. stretch | 466 | Ne | AB | Shnitko, Fulara, et al., 2008 | |
2 | Bend | 184 | Ne | AB | Shnitko, Fulara, et al., 2008 | ||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
b2 | 3 | Asym. stretch | 594.2 | T | Ar | IR | Brabson, Mielke, et al., 1991 |
Additional references: Jacox, 1994, page 110; Jacox, 2003, page 148
Notes
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
d | Photodissociation threshold |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B.,
Photoelectron spectroscopy of SO2-, S3-, and S2O-,
J. Phys. Chem., 1986, 90, 2574. [all data]
Hunsicker, Jones, et al., 1995
Hunsicker, S.; Jones, R.O.; Gantefor, G.,
Rings and chains in sulfur cluster anions S- to S-9(-): Theory (simulated annealing) and experiment (photoelectron detachment),
J. Chem. Phys., 1995, 102, 15, 5917, https://doi.org/10.1063/1.469326
. [all data]
Shnitko, Fulara, et al., 2008
Shnitko, I.; Fulara, J.; Garkusha, I.; Nagy, A.; Maier, J.P.,
Electronic transitions of and in neon matrixes,
Chem. Phys., 2008, 346, 1-3, 8, https://doi.org/10.1016/j.chemphys.2008.01.005
. [all data]
Brabson, Mielke, et al., 1991
Brabson, G.D.; Mielke, Z.; Andrews, L.,
Infrared spectra and structures of isotopically enriched sulfur (S3 and S4) in solid argon,
J. Phys. Chem., 1991, 95, 1, 79, https://doi.org/10.1021/j100154a019
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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