Silane, tetraphenyl-
- Formula: C24H20Si
- Molecular weight: 336.5011
- IUPAC Standard InChIKey: JLAVCPKULITDHO-UHFFFAOYSA-N
- CAS Registry Number: 1048-08-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraphenylsilane; Tetraphenylsilicon
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Gas phase ion energetics data
Go To: Top, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.6 | PE | Novak and Potts, 1984 | LBLHLM |
8.50 ± 0.03 | PI | Rodionov, Potapov, et al., 1973 | LLK |
8.65 ± 0.15 | EI | Gaidis, Briggs, et al., 1971 | LLK |
8.96 | PE | Novak and Potts, 1984 | Vertical value; LBLHLM |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C18H15Si+ | 9.7 | C6H5 | PI | Rodionov, Potapov, et al., 1973 | LLK |
C18H15Si+ | 9.93 ± 0.08 | C6H5 | EI | Gaidis, Briggs, et al., 1971 | LLK |
IR Spectrum
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | Copyright (C) 1987 by the Coblentz Society Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | DOW CORNING CORP. |
Source reference | COBLENTZ NO. 5592 |
Date | 1965/11/04 |
Name(s) | tetraphenylsilane |
State | SOLUTION (2% CCl4 FOR 3800-1300, 2% CS2 FOR 1300-650, AND 2% CCl4 FOR 650-250) |
Instrument | PERKIN-ELMER 521 (GRATING) |
Instrument parameters | FILTERS AT 3150, 2500, 2000, 1150, 700, 410. GRATING CHANGES: 2000, 630 |
Path length | 0.010 CM, 0.011 CM, AND 0.010 CM SPECTRAL CONTAMINATION DUE TO AN UNKNOWN AROUND 783 CM-1 |
Resolution | 2 |
Melting point | 237 C |
References
Go To: Top, Gas phase ion energetics data, IR Spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Novak and Potts, 1984
Novak, I.; Potts, A.W.,
The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives,
J. Organomet. Chem., 1984, 262, 17. [all data]
Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L.,
Photoionization of certain aromatic heteroorganic compounds,
High Energy Chem., 1973, 7, 249, In original 278. [all data]
Gaidis, Briggs, et al., 1971
Gaidis, J.M.; Briggs, P.R.; Shannon, T.W.,
Mass spectra of disilanes. Phenyl-silicon interaction and silicon-silicon bond strength,
J. Phys. Chem., 1971, 75, 974. [all data]
Notes
Go To: Top, Gas phase ion energetics data, IR Spectrum, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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