Phosphoramidous difluoride, dimethyl-
- Formula: C2H6F2NP
- Molecular weight: 113.0463
- IUPAC Standard InChIKey: GLCRDWZYRKGLLT-UHFFFAOYSA-N
- CAS Registry Number: 814-97-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: (Dimethylamino)difluorophosphine; Difluoro(dimethylamino)phosphine; Dimethylphosphoramidous difluoride; Dimethylaminodifluorphosphine
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.2 ± 0.3 | EI | Paine, Sodeck, et al., 1972 | |
9.60 | PE | Lappert, Pedley, et al., 1975 | Vertical value |
9.58 | PE | Cowley, Dewar, et al., 1973 | Vertical value |
9.6 | PE | Cradock and Rankin, 1972 | Vertical value |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Paine, Sodeck, et al., 1972
Paine, R.T.; Sodeck, G.; Stafford, F.E.,
Molecular beam mass spectra and pyrolyses of fluorophosphine-triborane(7) complexes. Formation and mass spectrum of triborane(7),
Inorg. Chem., 1972, 11, 2593. [all data]
Lappert, Pedley, et al., 1975
Lappert, M.F.; Pedley, J.B.; Wilkins, B.T.; Stelzer, O.; Unger, E.,
Bonding studies of compounds of boron and the group 3-5 elements. Part XIII. He(I) photoelectron spectra of phosphines RnPX3-n (R=Me or Bu'; X=H, Cl, or F; n=1-3), (Me2N)nPCl3-n(n=1-3), and (R2N)PF2(R=Me or Et),
J. Chem. Soc. Dalton Trans., 1975, 1207. [all data]
Cowley, Dewar, et al., 1973
Cowley, A.H.; Dewar, M.J.S.; Goodman, D.W.; Schweiger, J.R.,
Stereochemical dependence of lone pair interactions in the photoelectron spectra of nitrogen-phosphorus compounds,
J. Am. Chem. Soc., 1973, 95, 6506. [all data]
Cradock and Rankin, 1972
Cradock, S.; Rankin, D.W.H.,
Photoelectron spectra of PF2H some substituted difluorophosphines,
J. Chem. Soc. Faraday Trans. 2, 1972, 68, 940. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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