Dichlorosilylene

• Formula: Cl₂Si
• Molecular weight: 98.992
• CAS Registry Number: 13569-32-9
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
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• Data at other public NIST sites:
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A

State:   a

State:   X

Additional references: Jacox, 1994, page 101; Jacox, 1998, page 197; Tanimoto, Takeo, et al., 1989; Fujitake and Hirota, 1994

Notes

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ruzsicska, Jodhan, et al., 1985
Ruzsicska, B.P.; Jodhan, A.; Safarik, I.; Strausz, O.P.; Bell, T.N., Dichlorosilylene. The UV spectrum, Chem. Phys. Lett., 1985, 113, 1, 67, https://doi.org/10.1016/0009-2614(85)85012-0 . [all data]

Sausa and Ronn, 1985
Sausa, R.C.; Ronn, A.M., Infrared multiple photon dissociation of dichlorosilane: The production of electronically excited SiCl2, Chem. Phys., 1985, 96, 1, 183, https://doi.org/10.1016/0301-0104(85)80203-2 . [all data]

Washida, Matsumi, et al., 1985
Washida, N.; Matsumi, Y.; Hayashi, T.; Ibuki, T.; Hiraya, A.; Shobatake, K., Emission spectra of SiH(A 2Δ→X 2Π) and SiCl2(A 1B1→X 1A1) in the VUV photolyses of silane and chlorinated silanes, J. Chem. Phys., 1985, 83, 6, 2769, https://doi.org/10.1063/1.449227 . [all data]

Sameith, Monch, et al., 1986
Sameith, D.; Monch, J.P.; Tiller, H.-J.; Schade, K., Vibrational analysis of the UV emission spectrum of dichlorosilyl, SiCl2, Chem. Phys. Lett., 1986, 128, 5-6, 483, https://doi.org/10.1016/0009-2614(86)80658-3 . [all data]

Suzuki, Washida, et al., 1986
Suzuki, M.; Washida, N.; Inoue, G., Laser-induced fluorescence of the SiCl2 radical, Chem. Phys. Lett., 1986, 131, 1-2, 24, https://doi.org/10.1016/0009-2614(86)80511-5 . [all data]

Meijer, Heinze, et al., 1989
Meijer, G.; Heinze, J.; Meerts, W.L.; ter Meulen, J.J.; Hougen, J.T., High-resolution spectroscopy on the transition in SiCl2, J. Mol. Spectrosc., 1989, 138, 1, 251, https://doi.org/10.1016/0022-2852(89)90115-X . [all data]

Karolczak and Clouthier, 1993
Karolczak, J.; Clouthier, D.J., Pyrolysis jet spectroscopy of dichlorosilylene, Chem. Phys. Lett., 1993, 201, 5-6, 409, https://doi.org/10.1016/0009-2614(93)85093-4 . [all data]

Milligan and Jacox, 1968
Milligan, D.E.; Jacox, M.E., Matrix-Isolation Study of the Vacuum--Ultraviolet Photolysis of Dischlorosilane. The Infrared Spectrum of the Free Radical SiCl2, J. Chem. Phys., 1968, 49, 4, 1938, https://doi.org/10.1063/1.1670330 . [all data]

Hargittai, Schultz, et al., 1983
Hargittai, I.; Schultz, G.; Tremmel, J.; Kagramanov, N.D.; Maltsev, A.K.; Nefedov, O.M., Molecular structure of silicon dichloride and silicon dibromide from electron diffraction combined with mass spectrometry, J. Am. Chem. Soc., 1983, 105, 9, 2895, https://doi.org/10.1021/ja00347a061 . [all data]

Sekiya, Nishimura, et al., 1991
Sekiya, H.; Nishimura, Y.; Tsuji, M., New electronic emission from SiCl2, Chem. Phys. Lett., 1991, 176, 5, 477, https://doi.org/10.1016/0009-2614(91)90240-A . [all data]

Du, Chen, et al., 1991
Du, K.; Chen, X.; Setser, D.W., Identification of the SiCl2 (ã 3B1-X 1A1) emission system and a flow reactor source of SiCl2(ã 3B1), Chem. Phys. Lett., 1991, 181, 4, 344, https://doi.org/10.1016/0009-2614(91)80082-9 . [all data]

Ibuki, Kono, et al., 1997
Ibuki, T.; Kono, M.; Asari, Y.; Hiraya, A.; Shobatake, K., Photoabsorption and fluorescence cross sections of SiCl[sub 4] in the region of 6.2--31 eV, J. Chem. Phys., 1997, 106, 12, 4853, https://doi.org/10.1063/1.473534 . [all data]

Maass, Hauge, et al., 1972
Maass, G.; Hauge, R.H.; Margrave, J.L., The I.R. Spectra of Matrix-isolated SiBr2 and SiCl2, Z. Anorg. Allg. Chem., 1972, 392, 3, 295, https://doi.org/10.1002/zaac.19723920314 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Tanimoto, Takeo, et al., 1989
Tanimoto, M.; Takeo, H.; Matsumura, C.; Fujitake, M.; Hirota, E., Microwave spectroscopic detection of dichlorosilylene SiCl2 in the ground state, J. Chem. Phys., 1989, 91, 4, 2102, https://doi.org/10.1063/1.457070 . [all data]

Fujitake and Hirota, 1994
Fujitake, M.; Hirota, E., Spectrochim. Acta, 1994, 50A, 1345. [all data]

Notes

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