c-HNSO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 46000 T gas 238 269 Allegretti and Merer, 1972

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
gas 325 350 Allegretti and Merer, 1972

State:   A?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 5 NSO bend 285 T gas AB Allegretti and Merer, 1972

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NH stretch 3308.5 gas IR Carlotti, Di Lonardo, et al., 1976
Carlotti, Di Lonardo, et al., 1980
1 NH stretch 3308 w m Ar IR Allegretti and Merer, 1972
Tchir and Spratley, 1975
1 NH stretch 3303 N2 IR Tchir and Spratley, 1975
2 SO stretch 1257.58 s gas IR Richert, 1961
Carlotti, Di Lonardo, et al., 1980
Joo and Clouthier, 1996
2 SO stretch 1249 vs Ar IR Allegretti and Merer, 1972
Tchir and Spratley, 1975
2 SO stretch 1252 N2 IR Tchir and Spratley, 1975
3 NS stretch 1086.83 w gas IR Richert, 1961
Carlotti, Di Lonardo, et al., 1980
Joo, Harjanto, et al., 1996
3 NS stretch 1083 s Ar IR Allegretti and Merer, 1972
Tchir and Spratley, 1975
3 NS stretch 1094 N2 IR Tchir and Spratley, 1975
4 HNS bend 905.88 gas IR Richert, 1961
Carlotti, Di Lonardo, et al., 1980
Puskar, Robertson, et al., 2006
4 HNS bend 900 s Ar IR Allegretti and Merer, 1972
Tchir and Spratley, 1975
4 HNS bend 923 N2 IR Tchir and Spratley, 1975
5 NSO bend 447.85 m gas IR Richert, 1961
Carlotti, Di Lonardo, et al., 1980
Joo, Harjanto, et al., 1996
5 NSO bend 447 s Ar IR Allegretti and Merer, 1972
Tchir and Spratley, 1975
5 NSO bend 455 N2 IR Tchir and Spratley, 1975
a 6 Torsion 757.52 gas IR Richert, 1961
Carlotti, Di Lonardo, et al., 1980
Puskar, Robertson, et al., 2006
6 Torsion 755 vs Ar IR Allegretti and Merer, 1972
Tchir and Spratley, 1975
6 Torsion 774 N2 IR Tchir and Spratley, 1975

Additional references: Jacox, 1994, page 175; Jacox, 1998, page 240; Kirchhoff, 1969; Tchir and Spratley, 1975, 2; Tchir and Spratley, 1975, 3; Dal Borgo, Di Lonardo, et al., 1979; Carlotti, Di Lonardo, et al., 1980, 2

Notes

wWeak
mMedium
sStrong
vsVery strong
TTentative assignment or approximate value
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Allegretti and Merer, 1972
Allegretti, J.M.; Merer, A.J., Ultraviolet Absorption Spectrum of Thionylimide (HNSO), Can. J. Phys., 1972, 50, 4, 404, https://doi.org/10.1139/p72-058 . [all data]

Carlotti, Di Lonardo, et al., 1976
Carlotti, M.; Di Lonardo, G.; Galloni, G.; Trombetti, A., The ν1 progression of HNSO in the ground state, J. Mol. Spectrosc., 1976, 60, 1-3, 388, https://doi.org/10.1016/0022-2852(76)90142-9 . [all data]

Carlotti, Di Lonardo, et al., 1980
Carlotti, M.; Di Lonardo, G.; Galloni, G.; Trombetti, A., Infrared spectrum and vibrational potential function of thionylimide (HNSO), J. Mol. Spectrosc., 1980, 84, 1, 155, https://doi.org/10.1016/0022-2852(80)90249-0 . [all data]

Tchir and Spratley, 1975
Tchir, P.O.; Spratley, R.D., The Infrared Spectrum and Force Field of Matrix Isolated, Can. J. Chem., 1975, 53, 15, 2311, https://doi.org/10.1139/v75-324 . [all data]

Richert, 1961
Richert, H., Zur Struktur des monomeren Thionylimids, Z. Anorg. Allg. Chem., 1961, 309, 3-4, 171, https://doi.org/10.1002/zaac.19613090304 . [all data]

Joo and Clouthier, 1996
Joo, D.-L.; Clouthier, D.J., Determination of the molecular constants of interacting bright and dark states: Analysis of the high-resolution infrared spectrum of the S--O stretching fundamental of thionylimide, HNSO, J. Chem. Phys., 1996, 104, 22, 8852, https://doi.org/10.1063/1.471619 . [all data]

Joo, Harjanto, et al., 1996
Joo, D.-L.; Harjanto, H.H.; Clouthier, D.J., Analysis of the High-Resolution Fourier Transform Infrared Spectra of the ν3and ν5Bands of Thionylimide (HNSO), J. Mol. Spectrosc., 1996, 178, 1, 78, https://doi.org/10.1006/jmsp.1996.0159 . [all data]

Puskar, Robertson, et al., 2006
Puskar, L.; Robertson, E.G.; McNaughton, D., High-resolution FTIR spectroscopy of HNSO---Analysis of the highly perturbed ν4, ν6 and 2ν5 bands, J. Mol. Spectrosc., 2006, 240, 2, 244, https://doi.org/10.1016/j.jms.2006.10.001 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Kirchhoff, 1969
Kirchhoff, W.H., Microwave spectrum, structure, and dipole moment of cis-thionylimide, J. Am. Chem. Soc., 1969, 91, 10, 2437, https://doi.org/10.1021/ja01038a006 . [all data]

Tchir and Spratley, 1975, 2
Tchir, P.O.; Spratley, R.D., The Photolysis of Matrix Isolated, Can. J. Chem., 1975, 53, 15, 2318, https://doi.org/10.1139/v75-325 . [all data]

Tchir and Spratley, 1975, 3
Tchir, P.O.; Spratley, R.D., The Photolysis of Matrix Isolated, Can. J. Chem., 1975, 53, 15, 2331, https://doi.org/10.1139/v75-326 . [all data]

Dal Borgo, Di Lonardo, et al., 1979
Dal Borgo, A.; Di Lonardo, G.; Scappini, F.; Trombetti, A., Centrifugal distortion analysis of thionylimide, HNSO, Chem. Phys. Lett., 1979, 63, 1, 115, https://doi.org/10.1016/0009-2614(79)80470-4 . [all data]

Carlotti, Di Lonardo, et al., 1980, 2
Carlotti, M.; Di Lonardo, G.; Galloni, G.; Trombetti, A., The ν1 and 2ν1 bands of DNSO, J. Mol. Spectrosc., 1980, 80, 2, 291, https://doi.org/10.1016/0022-2852(80)90141-1 . [all data]

Notes

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