O3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E,F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 37680 ± 160 gas Brundle, 1974
Dyke, Golob, et al., 1974
Katsumata, Shiromaru, et al., 1984
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 1000 ± 40 gas PE Katsumata, Shiromaru, et al., 1984

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 29530 ± 160 gas Dyke, Golob, et al., 1974
Katsumata, Shiromaru, et al., 1984
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 850 ± 40 gas PE Katsumata, Shiromaru, et al., 1984

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 25580 ± 160 gas Dyke, Golob, et al., 1974
Katsumata, Shiromaru, et al., 1984

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 8960 ± 160 gas Frost, Lee, et al., 1974
Brundle, 1974
Dyke, Golob, et al., 1974
Katsumata, Shiromaru, et al., 1984
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 900 T gas PE Brundle, 1974
Katsumata, Shiromaru, et al., 1984

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 1089.7 ± 0.4 gas Frost, Lee, et al., 1974
Brundle, 1974
Dyke, Golob, et al., 1974
Katsumata, Shiromaru, et al., 1984
Willitsch, Innocenti, et al., 2005
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 1380 ± 40 gas PE Brundle, 1974
Katsumata, Shiromaru, et al., 1984

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 1050 ± 80 gas PI Weiss, Berkowitz, et al., 1977
2 Bend 616.8 ± 0.6 gas PE PI Frost, Lee, et al., 1974
Brundle, 1974
Dyke, Golob, et al., 1974
Weiss, Berkowitz, et al., 1977
Katsumata, Shiromaru, et al., 1984
2 Bend 616.8 ± 0.6 gas TPE Willitsch, Innocenti, et al., 2005

Additional references: Jacox, 1994, page 95

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brundle, 1974
Brundle, C.R., He (I) and He (II) photoelectron spectra of ozone, Chem. Phys. Lett., 1974, 26, 25. [all data]

Dyke, Golob, et al., 1974
Dyke, J.M.; Golob, L.; Jonathan, N.; Morris, A.; Okuda, M., J. Chem. Soc., 1974, Faraday Trans. 2 70, 1828. [all data]

Katsumata, Shiromaru, et al., 1984
Katsumata, S.; Shiromaru, H.; Kimura, T., Photoelectron angular distribution and assignment of photoelectron spectrum of ozone, Bull. Chem. Soc. Jpn., 1984, 57, 1784. [all data]

Frost, Lee, et al., 1974
Frost, D.C.; Lee, S.T.; McDowell, C.A., High resolution photoelectron spectroscopy of ozone, Chem. Phys. Lett., 1974, 24, 149. [all data]

Willitsch, Innocenti, et al., 2005
Willitsch, S.; Innocenti, F.; Dyke, J.M.; Merkt, F., High-resolution pulsed-field-ionization zero-kinetic-energy photoelectron spectroscopic study of the two lowest electronic states of the ozone cation O[sub 3][sup +], J. Chem. Phys., 2005, 122, 2, 024311, https://doi.org/10.1063/1.1829974 . [all data]

Weiss, Berkowitz, et al., 1977
Weiss, M.J.; Berkowitz, J.; Appelman, E.H., Photoionization of ozone: Formation of O4+ and O5+, J. Chem. Phys., 1977, 66, 2049. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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