OCuO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 20699 Ne 432 540 Bondybey and English, 1984
Caspary, Savchenko, et al., 2000

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 20486.5 Ar Tevault, 1982
Bondybey and English, 1984
Caspary, Savchenko, et al., 2000

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 20064 Kr Caspary, Savchenko, et al., 2000

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19686.9 Xe 440 586 Ozin, Mitchell, et al., 1983
Caspary, Savchenko, et al., 2000

State:   E'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13640 ± 160 gas Wu, Desai, et al., 1997

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 11309.5 Ne Caspary, Savchenko, et al., 2000
To = 11268.5 Xe Caspary, Savchenko, et al., 2000
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 636.8 Ne LF Caspary, Savchenko, et al., 2000
Πu 2 Bend 234 Ne LF Caspary, Savchenko, et al., 2000

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 11110.5 Ne Caspary, Savchenko, et al., 2000
To = 11060 Xe Caspary, Savchenko, et al., 2000
To = 6540 ± 160 gas Wu, Desai, et al., 1995
Wu, Desai, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 640.8 Ne LF Caspary, Savchenko, et al., 2000

State:   C'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 9680 ± 160 gas Wu, Desai, et al., 1997

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 6683.4 Xe Caspary, Savchenko, et al., 2000
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 569.7 Xe LF Caspary, Savchenko, et al., 2000

State:   B'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 5080 ± 160 gas Wu, Desai, et al., 1995
Wu, Desai, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
640 ± 80 gas PE Wu, Desai, et al., 1995
Wu, Desai, et al., 1997

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 3850 T Ne Bondybey and English, 1984
Caspary, Savchenko, et al., 2000
To = 3387.3 Xe Caspary, Savchenko, et al., 2000
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 590 Ne LF Bondybey and English, 1984
1 Sym. stretch 597.5 Xe LF Caspary, Savchenko, et al., 2000
Πu 2 Bend 113 Xe LF Caspary, Savchenko, et al., 2000

State:   A'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 2580 ± 160 gas Wu, Desai, et al., 1995
Wu, Desai, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
640 ± 80 gas PE Wu, Desai, et al., 1995
Wu, Desai, et al., 1997

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 CuO s-stretch 611.5 Ne LF Bondybey and English, 1984
Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 CuO s-stretch 627.5 Ar LF Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 CuO s-stretch 625.9 Ar LF Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 CuO s-stretch 608.1 Ar LF Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 CuO s-stretch 618.9 Xe AB LF Ozin, Mitchell, et al., 1983
Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 CuO s-stretch 614.1 N2 LF Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Πu 2 Bend 135.6 Ne LF Bondybey and English, 1984
Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Πu 2 Bend 118 Xe LF Caspary, Savchenko, et al., 2000

State:   ?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σu+ 3 Asym. stretch 628 Xe LF Caspary, Savchenko, et al., 2000

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 658 Ne LF Bondybey and English, 1984
Caspary, Savchenko, et al., 2000
1 Sym. stretch 668 Ar LF Tevault, 1982
1 Sym. stretch 664.2 Xe EM LF Ozin, Mitchell, et al., 1983
Caspary, Savchenko, et al., 2000
Πu 2 Bend 193.4 Ne LF Bondybey and English, 1984
Caspary, Savchenko, et al., 2000
2 Bend 161.5 Xe LF Caspary, Savchenko, et al., 2000
Σu+ 3 Asym. stretch 823.0 Ar IR Chertihin, Andrews, et al., 1997
3 Asym. stretch 826.7 N2 IR Chertihin, Andrews, et al., 1997

Additional references: Jacox, 1998, page 178; Jacox, 2003, page 107

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bondybey and English, 1984
Bondybey, V.E.; English, J.H., Structure of copper oxide (CuO2) and its photochemistry in rare gas matrixes, J. Phys. Chem., 1984, 88, 11, 2247, https://doi.org/10.1021/j150655a014 . [all data]

Caspary, Savchenko, et al., 2000
Caspary, N.; Savchenko, E.V.; Thoma, A.; Lammers, A.; Bondybey, V.E., Optical spectra of CuO[sub 2] and matrix effect upon its structure, Low Temp. Phys., 2000, 26, 9, 744, https://doi.org/10.1063/1.1312402 . [all data]

Tevault, 1982
Tevault, D.E., Laser-induced emission spectrum of CuO2 in argon matrices, J. Chem. Phys., 1982, 76, 6, 2859, https://doi.org/10.1063/1.443387 . [all data]

Ozin, Mitchell, et al., 1983
Ozin, G.A.; Mitchell, S.A.; Garcia-Prieto, J., Dioxygen activation by photoexcited copper atoms, J. Am. Chem. Soc., 1983, 105, 21, 6399, https://doi.org/10.1021/ja00359a006 . [all data]

Wu, Desai, et al., 1997
Wu, H.; Desai, S.R.; Wang, L., Chemical Bonding between Cu and Oxygen - Copper Oxides versus O2 Complexes: A Study of CuOx(x=0-6) Species by Anion Photoelectron Spectroscopy, J. Phys. Chem., 1997, 101, 11, 2103, https://doi.org/10.1021/jp9631442 . [all data]

Wu, Desai, et al., 1995
Wu, H.; Desai, S.R.; Wang, L., Two Isomers of CuO2: The CU(O2) complex and the Copper Dioxide, J. Chem. Phys., 1995, 103, 10, 4363, https://doi.org/10.1063/1.470676 . [all data]

Chertihin, Andrews, et al., 1997
Chertihin, G.V.; Andrews, L.; Bauschlicher, C.W., Jr., Reactions of Laser-Ablated Copper Atoms with Dioxygen. Infrared Spectra of the Copper Oxides CuO, OCuO, CuOCuO, and OCuOCuO and Superoxide CuOO in Solid Argon, J. Phys. Chem. A, 1997, 101, 22, 4026, https://doi.org/10.1021/jp9701653 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References