H2S+

• Formula: H₂S⁺
• Molecular weight: 34.080
• CAS Registry Number: 77544-69-5
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Options:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(H₂S⁺ • ) +  = (H₂S⁺ • 2)

By formula: (H₂S⁺ • H₂S) + H₂S = (H₂S⁺ • 2H₂S)

H₂S⁺ +  = (H₂S⁺ • )

By formula: H₂S⁺ + H₂S = (H₂S⁺ • H₂S)

(H₂S⁺ • 2) +  = (H₂S⁺ • 3)

By formula: (H₂S⁺ • 2H₂S) + H₂S = (H₂S⁺ • 3H₂S)

(H₂S⁺ • 3) +  = (H₂S⁺ • 4)

By formula: (H₂S⁺ • 3H₂S) + H₂S = (H₂S⁺ • 4H₂S)

(H₂S⁺ • 4) +  = (H₂S⁺ • 5)

By formula: (H₂S⁺ • 4H₂S) + H₂S = (H₂S⁺ • 5H₂S)

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

H₂S⁺ +  = (H₂S⁺ • )

By formula: H₂S⁺ + H₂S = (H₂S⁺ • H₂S)

(H₂S⁺ • ) +  = (H₂S⁺ • 2)

By formula: (H₂S⁺ • H₂S) + H₂S = (H₂S⁺ • 2H₂S)

(H₂S⁺ • 2) +  = (H₂S⁺ • 3)

By formula: (H₂S⁺ • 2H₂S) + H₂S = (H₂S⁺ • 3H₂S)

(H₂S⁺ • 3) +  = (H₂S⁺ • 4)

By formula: (H₂S⁺ • 3H₂S) + H₂S = (H₂S⁺ • 4H₂S)

(H₂S⁺ • 4) +  = (H₂S⁺ • 5)

By formula: (H₂S⁺ • 4H₂S) + H₂S = (H₂S⁺ • 5H₂S)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B

State:   A

State:   X

Additional references: Jacox, 1994, page 24; Jacox, 1998, page 135; Moehlmann and de Heer, 1975

Notes

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Prest, Tzeng, et al., 1983
Prest, H.F.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y., Photoionization study of (H₂S)₂ and (H₂S)₃, J. Am. Chem. Soc., 1983, 105, 7531. [all data]

Walters and Blais, 1981
Walters, E.A.; Blais, N.C., Molecular beam photoionization of (H₂S)n,n = 1 - 7, J. Chem. Phys., 1981, 75, 4208. [all data]

Potts and Price, 1972
Potts, A.W.; Price, W.C., Photoelectron spectra and valence shell orbital structures of groups V VI hydrides, Proc. R. Soc. London A:, 1972, 326, 181. [all data]

Hochlaf, Weitzel, et al., 2004
Hochlaf, M.; Weitzel, K.-M.; Ng, C.Y., Vacuum ultraviolet pulsed-field ionization-photoelectron study of H[sub 2]S in the energy range of 10--17 eV, J. Chem. Phys., 2004, 120, 15, 6944, https://doi.org/10.1063/1.1669386 . [all data]

Karlsson, Mattsson, et al., 1976
Karlsson, L.; Mattsson, L.; Jadrny, R.; Bergmark, T.; Siegbahn, K., Vibrational ans vibronic structure in the valence electron spectrum of H₂S, Phys. Scr., 1976, 13, 229. [all data]

Dixon, Duxbury, et al., 1971
Dixon, R.N.; Duxbury, G.; Horani, M.; Rostas, J., The H, Mol. Phys., 1971, 22, 6, 977, https://doi.org/10.1080/00268977100103311 . [all data]

Duxbury, Horani, et al., 1972
Duxbury, G.; Horani, M.; Rostas, J., Rotational Analysis of the Electronic Emission Spectrum of the HFormulaSFormula Ion Radical, Proc. Roy. Soc. (London) A331, 1972, 331, 1584, 109, https://doi.org/10.1098/rspa.1972.0167 . [all data]

Baltzer, Karlsson, et al., 1995
Baltzer, P.; Karlsson, L.; Lundqvist, M.; Wannberg, B.; Holland, D.M.P.; MacDonald, M.A., An experimental study of the valence shell photoelectron spectrum of hydrogen sulphide, Chem. Phys., 1995, 195, 1-3, 403, https://doi.org/10.1016/0301-0104(95)00053-Q . [all data]

Han, Kang, et al., 2010
Han, S.; Kang, T.Y.; Kim, S.K., Rotationally resolved spectroscopy of the A [sup 2]A[sub 1]←X [sup 2]B[sub 1] transition of H[sub 2]S[sup +] above the barrier to linearity using the mass-analyzed threshold ionization photofragment excitation technique, J. Chem. Phys., 2010, 132, 12, 124304, https://doi.org/10.1063/1.3358252 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Moehlmann and de Heer, 1975
Moehlmann, G.R.; de Heer, F.J., Lifetimes of the vibronic Ã2A1 states of H2S+, Chem. Phys. Lett., 1975, 36, 3, 353, https://doi.org/10.1016/0009-2614(75)80254-5 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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