N≡CCHS
- Formula: C2HNS
- Molecular weight: 71.101
- CAS Registry Number: 87598-22-9
- Information on this page:
- Data at other public NIST sites:
- Options:
Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
View reactions leading to C2HNS+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.65 ± 0.16 | IMRB | Born, Ingemann, et al., 1996 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 2 | CN stretch | 2221 | Ar | IR | Kappe, Wong, et al., 1993 | |
| 3 | CH rock | 1320 | Ar | IR | Kappe, Wong, et al., 1993 | ||
| 4 | CS stretch | 1103 | Ar | IR | Kappe, Wong, et al., 1993 | ||
| 5 | CC stretch | 889 | Ar | IR | Kappe, Wong, et al., 1993 | ||
| a | 8 | CH wag | 824 | Ar | IR | Kappe, Wong, et al., 1993 | |
Additional references: Jacox, 1998, page 288; Bogey, Demuynck, et al., 1989
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Born, Ingemann, et al., 1996
Born, M.; Ingemann, S.; Nibbering, N.M.M.,
Experimental Determination of the Enthalpies of Formation of Formyl Cyanide and Thioformyl Cyanide in the Gas Phase,
J. Phys. Chem., 1996, 100, 44, 17662, https://doi.org/10.1021/jp9609141
. [all data]
Kappe, Wong, et al., 1993
Kappe, C.O.; Wong, M.W.; Wentrup, C.,
Matrix isolation and infrared spectrum of thioformyl cyanide,
Tetrahed. Lett., 1993, 34, 41, 6623, https://doi.org/10.1016/0040-4039(93)88121-X
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Bogey, Demuynck, et al., 1989
Bogey, M.; Demuynck, C.; Destombes, J.-L.; Gaumont, A.; Denis, J.-M.; Vallee, Y.; Ripoll, J.-L.,
Thioformyl cyanide. Gas-phase synthesis and millimeter wave spectrum,
J. Am. Chem. Soc., 1989, 111, 19, 7399, https://doi.org/10.1021/ja00201a018
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.