Antimony monosulfide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
8.4 ± 0.3EISullivan, Prusaczyk, et al., 1970

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Sb+16.4 ± 0.3?EISullivan, Prusaczyk, et al., 1970 

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through July, 1977

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for (121)Sb32S
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
Additional unassigned emission bands (both V and R shaded) in the region 12000 - 28500 cm-1.
Shimauchi and Nishiyama, 1968
G  (380) H (4.4)        G → (X) R 24626.0 H
Shimauchi and Nishiyama, 1968
           G → (X) R 27026.6 H
Shimauchi and Nishiyama, 1968
F  (296) H         F ↔ X R 27406.0 H
Shimauchi and Nishiyama, 1968
           F ↔ X R 28664.0 H
Shimauchi and Nishiyama, 1968
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
E  (442) H         E ↔ X R 26248.3 H
missing citation
           E ↔ X R 26720.4 H
missing citation
D  (389) H         D ↔ X R 24310.4 H
missing citation
C  (390) H         C → X R 23249.3 H
missing citation
           C → X R 25996.4 H
missing citation
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
B  (397) H (16.5)        B → (X) R 22517.2 H
missing citation
A  (341) H         A ↔ X R 19472.6 H
missing citation
           A ↔ X R 22278.9 H
missing citation
X 2Πr  (470) H (1.6)         
  (480) H (1.2)         

References

Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sullivan, Prusaczyk, et al., 1970
Sullivan, C.L.; Prusaczyk, J.E.; Carlson, K.D., Molecules in the equilibrium vaporization of antimony sulfide and selenide, J. Chem. Phys., 1970, 53, 1289. [all data]

Shimauchi and Nishiyama, 1968
Shimauchi, M.; Nishiyama, Y., The emission spectrum of the SbS radical, Sci. Light (Tokyo), 1968, 17, 76. [all data]


Notes

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