HO2CH2OH
- Formula: CH4O3
- Molecular weight: 64.0407
- CAS Registry Number: 15932-89-5
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| OH stretch | 3647.8 | s | gas | IR | Niki, Maker, et al., 1980 Fry, Matthews, et al., 2006 | ||
| OH stretch | 3598.1 | m s | gas | IR | Niki, Maker, et al., 1980 Fry, Matthews, et al., 2006 | ||
| CH stretch | 2947.2 | w m | gas | IR | Su, Calvert, et al., 1979 Fry, Matthews, et al., 2006 | ||
| OOH bend | 1344.9 | s | gas | IR | Su, Calvert, et al., 1979 Fry, Matthews, et al., 2006 | ||
| CO stretch | 1049.5 | vs | gas | IR | Su, Calvert, et al., 1979 Fry, Matthews, et al., 2006 | ||
| OO stretch | 820 | T | gas | IR | Su, Calvert, et al., 1979 | ||
Additional references: Jacox, 1994, page 379; Bauerle and Moortgat, 1999
Notes
| w | Weak |
| m | Medium |
| s | Strong |
| vs | Very strong |
| T | Tentative assignment or approximate value |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Niki, Maker, et al., 1980
Niki, H.; Maker, P.D.; Savage, C.M.; Breitenbach, L.P.,
Further IR spectroscopic evidence for the formation of CH2(OH)OOH in the gas-phase reaction of HO2 with CH2O,
Chem. Phys. Lett., 1980, 75, 3, 533, https://doi.org/10.1016/0009-2614(80)80571-9
. [all data]
Fry, Matthews, et al., 2006
Fry, J.L.; Matthews, J.; Lane, J.R.; Roehl, C.M.; Sinha, A.; Kjaergaard, H.G.; Wennberg, P.O.,
OH-Stretch Vibrational Spectroscopy of Hydroxymethyl Hydroperoxide,
J. Phys. Chem. A, 2006, 110, 22, 7072, https://doi.org/10.1021/jp0612127
. [all data]
Su, Calvert, et al., 1979
Su, F.; Calvert, J.G.; Shaw, J.H.; Niki, H.; Maker, P.D.; Savage, C.M.; Breitenbach, L.P.,
Spectroscopic and kinetic studies of a new metastable species in the photooxidation of gaseous formaldehyde,
Chem. Phys. Lett., 1979, 65, 2, 221, https://doi.org/10.1016/0009-2614(79)87053-0
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Bauerle and Moortgat, 1999
Bauerle, S.; Moortgat, G.K.,
Absorption cross-sections of HOCH2OOH vapor between 205 and 360 nm at 298 K,
Chem. Phys. Lett., 1999, 309, 1-2, 43, https://doi.org/10.1016/S0009-2614(99)00652-1
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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