BF2OH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 OH stretch 3712.5 s Ne IR Jacox, Irikura, et al., 2000
2 BF2, BO stretch 1464.3 vs Ne IR Jacox, Irikura, et al., 2000
3 BF2 a-stretch 1414.9 vs Ne IR Jacox, Irikura, et al., 2000
4 BOH deform. 961.49 gas IR Collet, Perrin, et al., 2002
Perrin, Bertseva, et al., 2007
4 BOH deform. 959.1 s Ne IR Jacox, Irikura, et al., 2000
5 BF2, BO stretch 880.74 gas IR Breidung, Demaison, et al., 2004
Perrin, Carvajal-Zaera, et al., 2004
5 BF2, BO stretch 879.3 w m Ne IR Jacox, Irikura, et al., 2000
6 479.17 gas IR Breidung, Demaison, et al., 2004
Perrin, Carvajal-Zaera, et al., 2004
7 Deformation 446.54 gas IR Breidung, Demaison, et al., 2004
Perrin, Carvajal-Zaera, et al., 2004
7 Deformation 447.5 m Ne IR Jacox, Irikura, et al., 2000
a 8 OPLA 684.16 gas IR Collet, Perrin, et al., 2002
Perrin, Carvajal-Zaera, et al., 2004
8 OPLA 680.9 m s Ne IR Jacox, Irikura, et al., 2000
9 Torsion 522.87 gas IR Collet, Perrin, et al., 2002
Perrin, Carvajal-Zaera, et al., 2004
9 Torsion 520.8 m s Ne IR Jacox, Irikura, et al., 2000

Additional references: Jacox, 2003, page 274; Takeo and Curl, 1972; Vormann and Dreizler, 1989; Coudert, Garcia-Fernandez, et al., 2008

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacox, Irikura, et al., 2000
Jacox, M.E.; Irikura, K.K.; Thompson, W.E., The reaction of BF[sub 3] with H[sub 2]O: Infrared spectrum of BF[sub 2]OH trapped in solid neon, J. Chem. Phys., 2000, 113, 14, 5705, https://doi.org/10.1063/1.1290287 . [all data]

Collet, Perrin, et al., 2002
Collet, D.; Perrin, A.; Burger, H.; Flaud, J.-M., First Gas Phase Infrared Spectroscopy of F2BOH: High-Resolution Study of the ν8 and ν9 Bands, J. Mol. Spectrosc., 2002, 212, 1, 118, https://doi.org/10.1006/jmsp.2001.8509 . [all data]

Perrin, Bertseva, et al., 2007
Perrin, A.; Bertseva, E.; Flaud, J.-M.; Collet, D.; Burger, H.; Masiello, T.; Blake, T.A., High resolution infrared study of the 2ν, Mol. Phys., 2007, 105, 13-14, 1833, https://doi.org/10.1080/00268970701426992 . [all data]

Breidung, Demaison, et al., 2004
Breidung, J.; Demaison, J.; D'Eu, J.-F.; Margules, L.; Collet, D.; Mkadmi, E.B.; Perrin, A.; Thiel, W., Ground-state constants, ab initio anharmonic force field, and equilibrium structure of F2BOH, J. Mol. Spectrosc., 2004, 228, 1, 7, https://doi.org/10.1016/j.jms.2004.06.009 . [all data]

Perrin, Carvajal-Zaera, et al., 2004
Perrin, A.; Carvajal-Zaera, M.; Dutkiewicz, Z.; Flaud, J.-M.; Collet, D.; Burger, H.; Demaison, J.; Willaert, F.; Mader, H.; Larsen, N.W., High-resolution infrared and microwave study of, Mol. Phys., 2004, 102, 14-15, 1641, https://doi.org/10.1080/00268970410001725756 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Takeo and Curl, 1972
Takeo, H.; Curl, R.F., Microwave Spectrum of BF2OH, J. Chem. Phys., 1972, 56, 9, 4314, https://doi.org/10.1063/1.1677864 . [all data]

Vormann and Dreizler, 1989
Vormann, K.; Dreizler, H., Z. Naturforsch. A, 1989, 44, 1191. [all data]

Coudert, Garcia-Fernandez, et al., 2008
Coudert, L.H.; Garcia-Fernandez, P.; Mader, H.; Demaison, J.; Boggs, J.E., Ab Initio and Experimental Studies of the Large-Amplitude Motion in BF, J. Phys. Chem. A, 2008, 112, 7, 1536, https://doi.org/10.1021/jp709852p . [all data]

Notes

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