NiCN

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19127.2 gas Kingston, Merer, et al., 2002
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 3 NiC stretch 426.2 gas LF Kingston, Merer, et al., 2002

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 17811.8 gas Kingston, Merer, et al., 2002
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 163.1 gas LF Kingston, Merer, et al., 2002
Σ+ 3 NiC stretch 424.4 gas LF Kingston, Merer, et al., 2002

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16686.1 gas Kingston, Merer, et al., 2002
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 170.0 gas LF Kingston, Merer, et al., 2002
Σ+ 3 NiC stretch 425.9 gas LF Kingston, Merer, et al., 2002

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16607.3 gas Kingston, Merer, et al., 2002
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 180.2 gas LF Kingston, Merer, et al., 2002
Σ+ 3 NiC stretch 433.0 gas LF Kingston, Merer, et al., 2002

State:   W1
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 2238 gas Kingston, Merer, et al., 2002
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend (w) 225 ± 6 gas LF Kingston, Merer, et al., 2002
Σ+ 3 NiC stretch (w) 482 ± 7 gas LF Kingston, Merer, et al., 2002

State:   X2
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 830 gas Kingston, Merer, et al., 2002
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend (w) 225 ± 10 gas LF Kingston, Merer, et al., 2002
Σ+ 3 NiC stretch (w) 511 ± 18 gas LF Kingston, Merer, et al., 2002

State:   X1

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 244 gas LF Kingston, Merer, et al., 2002
Σ+ 3 NiC stretch 524 gas LF Kingston, Merer, et al., 2002
3 NiC stretch 455 gas LF Kingston, Merer, et al., 2002

Additional references: Sheridan and Ziurys, 2003

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kingston, Merer, et al., 2002
Kingston, C.T.; Merer, A.J.; Varberg, T.D., The Electronic Spectrum of NiCN in the Visible Region, J. Mol. Spectrosc., 2002, 215, 1, 106, https://doi.org/10.1006/jmsp.2002.8608 . [all data]

Sheridan and Ziurys, 2003
Sheridan, P.M.; Ziurys, L.M., Further studies of 3d transition metal cyanides: The pure rotational spectrum of NiCN (X [sup 2]Δ[sub i]), J. Chem. Phys., 2003, 118, 14, 6370, https://doi.org/10.1063/1.1557471 . [all data]

Notes

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