Cl3-

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 47360 gas Kaledin, Heaven, et al., 1999

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 41700 gas Kaledin, Heaven, et al., 1999

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 39530 Ar Andrews, 1976
Hacaloglu and Andrews, 1989

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 225 T Cs Ar Ra Ault and Andrews, 1976
1 Sym. stretch 253 Rb Ar Ra Ault and Andrews, 1976
1 Sym. stretch 258 K Ar Ra Ault and Andrews, 1976
1 Sym. stretch 276 Na Ar Ra Ault and Andrews, 1976
Σu+ 3 Asym. stretch 327 Cs Ar IR Ra Ault and Andrews, 1976
3 Asym. stretch 340 Rb Ar IR Ra Ault and Andrews, 1976
3 Asym. stretch 345 K Ar IR Ra Ault and Andrews, 1976
3 Asym. stretch 375 Na Ar IR Ra Ault and Andrews, 1976
3 Asym. stretch 374 Kr IR Nelson and Pimentel, 1967

Additional references: Jacox, 1994, page 119; Jacox, 2003, page 153; Wight, Ault, et al., 1976

Notes

TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold
NaInteraction with sodium.
KInteraction with potassium
RbInteraction with rubidium
CsInteraction with cesium

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kaledin, Heaven, et al., 1999
Kaledin, A.L.; Heaven, M.C.; Morokuma, K.; Neumark, D.M., Cl3- electron photodetachment spectrum: measurement and assignment, Chem. Phys. Lett., 1999, 306, 1-2, 48, https://doi.org/10.1016/S0009-2614(99)00419-4 . [all data]

Andrews, 1976
Andrews, L., Optical spectra of the difluoride, dichloride, and trichloride ions in the matrix-isolated M+F2-, M+Cl2-, and M+Cl3- species, J. Am. Chem. Soc., 1976, 98, 8, 2147, https://doi.org/10.1021/ja00424a022 . [all data]

Hacaloglu and Andrews, 1989
Hacaloglu, J.; Andrews, L., A chemical ionization source of molecular ions for matrix-isolation spectroscopy, Chem. Phys. Lett., 1989, 160, 3, 274, https://doi.org/10.1016/0009-2614(89)87595-5 . [all data]

Ault and Andrews, 1976
Ault, B.S.; Andrews, L., Infrared spectra of the M+HBr2- and the M+HClBr- ion pairs and their deuterium analogs isolated in argon matrices at 15 K, J. Chem. Phys., 1976, 64, 5, 1986, https://doi.org/10.1063/1.432463 . [all data]

Nelson and Pimentel, 1967
Nelson, L.Y.; Pimentel, G.C., Infrared Detection of the Trichloride Radical, Cl3, J. Chem. Phys., 1967, 47, 9, 3671, https://doi.org/10.1063/1.1712442 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Wight, Ault, et al., 1976
Wight, C.A.; Ault, B.S.; Andrews, L., On microwave discharge sources of new chemical species for matrix-isolation spectroscopy and the identification of charged species, J. Chem. Phys., 1976, 65, 4, 1244, https://doi.org/10.1063/1.433233 . [all data]

Notes

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