CdCH3

• Formula: CH₃Cd
• Molecular weight: 127.446
• CAS Registry Number: 42217-97-0
• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₂H₆Cd (g) = CH₃Cd (g) +  (g)

By formula: C₂H₆Cd (g) = CH₃Cd (g) + CH₄ (g)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   A

State:   X

Additional references: Jacox, 1994, page 231; Jacox, 1998, page 268; Jacox, 2003, page 250

Notes

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Jackson, 1989
Jackson, R.L., Chem. Phys. Lett., 1989, 163, 315. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Young, Gosavi, et al., 1973
Young, P.J.; Gosavi, R.K.; Connor, J.; Strausz, O.P.; Gunning, H.E., Ultraviolet absorption spectra of CdCH3, ZnCH3, and TeCH3, J. Chem. Phys., 1973, 58, 12, 5280, https://doi.org/10.1063/1.1679141 . [all data]

Ellis, Robles, et al., 1992
Ellis, A.M.; Robles, E.S.J.; Miller, T.A., Dispersed fluorescence spectroscopy and fluorescence lifetime measurements of excited vibrational levels of CdCH3, Chem. Phys. Lett., 1992, 190, 6, 599, https://doi.org/10.1016/0009-2614(92)85196-H . [all data]

Yu, Youngs, et al., 1986
Yu, C.F.; Youngs, F.; Tsukiyama, K.; Bersohn, R.; Preses, J., Photodissociation dynamics of cadmium and zinc dimethyl, J. Chem. Phys., 1986, 85, 3, 1382, https://doi.org/10.1063/1.451226 . [all data]

Suto, Ye, et al., 1988
Suto, M.; Ye, C.; Lee, L.C., Quantitative absorption and fluorescence spectroscopy of Cd(CH3)2 in vacuum ultraviolet, J. Chem. Phys., 1988, 89, 1, 160, https://doi.org/10.1063/1.455499 . [all data]

Ibuki, Hiraya, et al., 1990
Ibuki, T.; Hiraya, A.; Shobatake, K., Photoexcitation of M(CH3)2 (M=Zn, Cd, Hg) compounds in the 106--270 nm region, J. Chem. Phys., 1990, 92, 5, 2797, https://doi.org/10.1063/1.457926 . [all data]

Penner, Amirav, et al., 1991
Penner, A.; Amirav, A.; Bersohn, R., Emission spectrum of CdCH3, Chem. Phys. Lett., 1991, 176, 2, 147, https://doi.org/10.1016/0009-2614(91)90146-Z . [all data]

Robles, Ellis, et al., 1991
Robles, E.S.J.; Ellis, A.M.; Miller, T.A., Laser-induced fluorescence spectra of the cold radicals, ZnCH3 and CdCH3, and their inert-gas complexes, X«58872»CdCH3 (X = He, Ne, Ar, Kr, Xe), Chem. Phys. Lett., 1991, 178, 2-3, 185, https://doi.org/10.1016/0009-2614(91)87054-F . [all data]

Cerny, Tan, et al., 1993
Cerny, T.M.; Tan, X.Q.; Williamson, J.M.; Robles, E.S.J.; Ellis, A.M.; Miller, T.A., High resolution electronic spectroscopy of ZnCH3 and CdCH3, J. Chem. Phys., 1993, 99, 12, 9376, https://doi.org/10.1063/1.465521 . [all data]

Tan, Cerny, et al., 1994
Tan, X.Q.; Cerny, T.M.; Williamson, J.M.; Miller, T.A., Hyperfine structure in the electronic spectra of the CdH and CdCH3 radicals, J. Chem. Phys., 1994, 101, 8, 6396, https://doi.org/10.1063/1.468396 . [all data]

Panov, Powers, et al., 1998
Panov, S.I.; Powers, D.E.; Miller, T.A., The spectroscopy of the CdCH[sub 3] radical and its positive ion, J. Chem. Phys., 1998, 108, 4, 1335, https://doi.org/10.1063/1.475506 . [all data]

Pushkarsky, Barckholtz, et al., 1999
Pushkarsky, M.B.; Barckholtz, T.A.; Miller, T.A., J. Ch3m. Phys., 1999, 110, 2016. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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