FN3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 58000 ± 1050 gas Rademacher, Bittner, et al., 1988

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 45670 ± 480 gas Rademacher, Bittner, et al., 1988

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 39450 ± 1050 gas Rademacher, Bittner, et al., 1988

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 37030 ± 1050 gas Rademacher, Bittner, et al., 1988

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 21860 ± 480 gas Rademacher, Bittner, et al., 1988
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 N3 a-stretch 1800 T gas PE Rademacher, Bittner, et al., 1988

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 N3 s-stretch 800 T gas PE Rademacher, Bittner, et al., 1988

Additional references: Jacox, 1994, page 196

Notes

TTentative assignment or approximate value
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rademacher, Bittner, et al., 1988
Rademacher, P.; Bittner, A.J.; Schatte, G.; Willner, H., Photoelectron Spectrum and Electronic Structure of Triazadienyl Fluoride, N3F, Chem. Ber., 1988, 121, 3, 555, https://doi.org/10.1002/cber.19881210325 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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