Dimethylgermathione
- Formula: C2H6GeS
- Molecular weight: 134.77
- CAS Registry Number: 16090-49-6
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 3 | CH3 deform. | 1407 | Ar | IR | Khabashesku, Boganov, et al., 1991 | |
| 4 | CH3 deform. | 1237 | Ar | IR | Khabashesku, Boganov, et al., 1991 | ||
| 5 | CH3 rock | 850 | s | Ar | IR | Barrau, Balaji, et al., 1989 Khabashesku, Boganov, et al., 1991 | |
| 6 | Ge=S stretch | 605 | vs | Ar | IR | Barrau, Balaji, et al., 1989 Khabashesku, Boganov, et al., 1991 | |
| 7 | GeC s-stretch | 516 | m | Ar | IR | Barrau, Balaji, et al., 1989 Khabashesku, Boganov, et al., 1991 | |
| b1 | 14 | CH3 a-deform. | 1390 | m | Ar | IR | Barrau, Balaji, et al., 1989 Khabashesku, Boganov, et al., 1991 |
| 15 | CH3 deform | 761 | m | Ar | IR | Barrau, Balaji, et al., 1989 Khabashesku, Boganov, et al., 1991 | |
| b2 | 21 | CH3 deform | 1229 | m | Ar | IR | Barrau, Balaji, et al., 1989 Khabashesku, Boganov, et al., 1991 |
| 22 | CH3 rock | 809 | Ar | IR | Khabashesku, Boganov, et al., 1991 | ||
| 23 | GeC a-stretch | 574 | Ar | IR | Khabashesku, Boganov, et al., 1991 | ||
Additional references: Jacox, 2003, page 391
Notes
| m | Medium |
| s | Strong |
| vs | Very strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Khabashesku, Boganov, et al., 1991
Khabashesku, V.N.; Boganov, S.E.; Zuev, P.S.; Nefedov, O.M., et al.,
Direct study of unstable dimethylgermathione, Me2Ge«58875»S, by vacuum pyrolysis-MS and low temperature matrix IR spectroscopy,
J. Organomet. Chem., 1991, 402, 2, 161, https://doi.org/10.1016/0022-328X(91)83060-H
. [all data]
Barrau, Balaji, et al., 1989
Barrau, J.; Balaji, V.; Michl, J.,
Matrix isolation and IR spectroscopy of germanethione Me2Ge:S,
Organomet., 1989, 8, 8, 2034, https://doi.org/10.1021/om00110a033
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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