Tert-butyl radical

• Formula: C₄H₉
• Molecular weight: 57.1143
• CAS Registry Number: 1605-73-8
• Information on this page:
  • Gas phase thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Gas phase thermochemistry data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   3d

State:   3p

State:   3s

State:   X

Additional references: Jacox, 1994, page 384

Notes

References

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tsang, 1996
Tsang, W., Heats of Formation of Organic Free Radicals by Kinetic Methods in Energetics of Organic Free Radicals, Martinho Simoes, J.A.; Greenberg, A.; Liebman, J.F., eds., Blackie Academic and Professional, London, 1996, 22-58. [all data]

Parkes and Quinn, 1975
Parkes, D.A.; Quinn, C.P., The ultraviolet absorption spectrum of tert-butyl radicals and the rate constant for their recombination, Chem. Phys. Lett., 1975, 33, 3, 483, https://doi.org/10.1016/0009-2614(75)85757-5 . [all data]

Parkes and Quinn, 1976
Parkes, D.A.; Quinn, C.P., J. Chem. Soc., 1976, Faraday Trans. 1 72, 1952. [all data]

Wendt and Hunziker, 1984
Wendt, H.R.; Hunziker, H.E., The UV spectra of primary, secondary, and tertiary alkyl radicals, J. Chem. Phys., 1984, 81, 2, 717, https://doi.org/10.1063/1.447755 . [all data]

Pacansky and Chang, 1981
Pacansky, J.; Chang, J.S., Infrared matrix isolation studies on the t-butyl radical, J. Chem. Phys., 1981, 74, 10, 5539, https://doi.org/10.1063/1.440916 . [all data]

Schrader, Pacansky, et al., 1984
Schrader, B.; Pacansky, J.; Pfeiffer, U., Calculation of the frequencies and intensities in the infrared spectra of matrix-isolated tert-butyl radical and isobutane, J. Phys. Chem., 1984, 88, 18, 4069, https://doi.org/10.1021/j150662a043 . [all data]

Bethune, 1981
Bethune, D.S., J. R. Lankard, 1981, P. P. Sorokin, A. J. Schell-Sorokin, R. M. Plecenik, and Ph. Avouris, J. Chem. Phys. 75, 2231. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  ΔfH°gas

  Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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