SF4+

• Formula: F₄S⁺
• Molecular weight: 108.058
• CAS Registry Number: 12528-36-8
• Information on this page:
  • Reaction thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(F₄S⁺ • F₆S^-) + F₆S^- = (F₄S⁺ • 2F₆S^-)

By formula: (F₄S⁺ • F₆S^-) + F₆S^- = (F₄S⁺ • 2F₆S^-)

F₄S⁺ + F₆S^- = (F₄S⁺ • F₆S^-)

By formula: F₄S⁺ + F₆S^- = (F₄S⁺ • F₆S^-)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?

State:   ?

State:   ?

State:   C,D

State:   A,B

State:   X

Additional references: Jacox, 1998, page 307; Jacox, 2003, page 307

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M. Fujimaki, Gas-Phase Stability of Cluster Ions SFm+(SF6)n with m = 0-5 and n = 1-3, J. Am. Soc. Mass Spectrom., 1995, 6, 12, 1137, https://doi.org/10.1016/1044-0305(95)00583-8 . [all data]

Cowley, Lattman, et al., 1979
Cowley, A.H.; Lattman, M.; Walker, M.L., A photoelectron spectroscopic-molecular orbital study of sulfur tetrafluoride and related fluorosulfuranes, J. Am. Chem. Soc., 1979, 101, 15, 4074, https://doi.org/10.1021/ja00509a011 . [all data]

Costa, Lloyd, et al., 1981
Costa, N.C.V.; Lloyd, D.R.; Roberts, P.J.; Cruickshank, D.W.J.; Avramides, E.; Chablo, A.; Collins, G.A.D., et al., J. Chem. Soc., 1981, Faraday Trans. 2 77, 899. [all data]

Jochims, Ruhl, et al., 1989
Jochims, H.-W.; Ruhl, E.; Baumgartel, H., Z. Naturforsch., 1989, 44b, 13. [all data]

Lugez, Jacox, et al., 1998
Lugez, C.L.; Jacox, M.E.; King, R.A.; Schaefer, H.F., III, Experimental and ab initio study of the infrared spectra of ionic species derived from SF[sub 6] and SF[sub 4] and trapped in solid neon, J. Chem. Phys., 1998, 108, 23, 9639, https://doi.org/10.1063/1.476440 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
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