PF3+

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 61500 ± 200 L gas Basset and Lloyd, 1972
Maier and Turner, 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 PF stretch 660 ± 30 gas PE Maier and Turner, 1972
2 Umbrella 360 ± 30 gas PE Maier and Turner, 1972

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 55000 ± 200 L gas Basset and Lloyd, 1972
Maier and Turner, 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 PF stretch 690 ± 30 gas PE Maier and Turner, 1972
2 Umbrella 395 ± 30 gas PE Maier and Turner, 1972

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 45500 ± 200 L gas Basset and Lloyd, 1972
Maier and Turner, 1972

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 39300 ± 600 L gas Basset and Lloyd, 1972
Maier and Turner, 1972

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 31220 ± 500 L gas Basset and Lloyd, 1972
Maier and Turner, 1972

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 PF stretch 940.0 m s Ne IR Lugez, Irikura, et al., 1998
2 Umbrella 475 ± 30 gas PE Basset and Lloyd, 1972
Maier and Turner, 1972
2 Umbrella 465.1 m s Ne IR Lugez, Irikura, et al., 1998
e 3 PF stretch 1097.5 s Ne IR Lugez, Irikura, et al., 1998

Additional references: Jacox, 1994, page 219; Jacox, 2003, page 242; Berkowitz and Greene, 1984; Berkowitz, Greene, et al., 1984

Notes

mMedium
sStrong
LLower bound
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Basset and Lloyd, 1972
Basset, P.J.; Lloyd, D.R., Photoelectron spectra of halides. Part III. Trifluorides and oxide trifluorides of nitrogen and phosphorus, and phosphorus oxide trichloride, J. Chem. Soc. Dalton Trans., 1972, 248. [all data]

Maier and Turner, 1972
Maier, J.P.; Turner, D.W., J. Chem. Soc., 1972, Faraday Trans. 2 68, 711. [all data]

Lugez, Irikura, et al., 1998
Lugez, C.L.; Irikura, K.K.; Jacox, M.E., Experimental and ab initio study of the infrared spectra of ionic species derived from PF[sub 5], PF[sub 3], and F[sub 3]PO and trapped in solid neon, J. Chem. Phys., 1998, 108, 20, 8381, https://doi.org/10.1063/1.476304 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Berkowitz and Greene, 1984
Berkowitz, J.; Greene, J.P., Vibrational autoionization in PF3: Doing violence to the propensity rule, J. Chem. Phys., 1984, 81, 10, 4328, https://doi.org/10.1063/1.447443 . [all data]

Berkowitz, Greene, et al., 1984
Berkowitz, J.; Greene, J.P.; Foropoulos, J., Jr.; Neskovic, O.M., Bonding and ionization energies of N-F and P-F compounds, J. Chem. Phys., 1984, 81, 6166. [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References