Methane, nitroso-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2Methane, nitroso- = C2H6N2O2

By formula: 2CH3NO = C2H6N2O2

Quantity Value Units Method Reference Comment
Δr-16.0kcal/molEqkChristie, Frost, et al., 1965gas phase

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' CH3 a-stretch 2991 w m Ar IR Barnes, Hallam, et al., 1976
CH3 s-stretch 2901 w m Ar IR Barnes, Hallam, et al., 1976
N=O stretch 1564 gas IR Luttke, 1957
N=O stretch 1549 s Ar IR Barnes, Hallam, et al., 1976
CH3 s-deform. 1348 s Ar IR Barnes, Hallam, et al., 1976
CH3 rock 967 w Ar IR Barnes, Hallam, et al., 1976
C-N stretch 842 gas IR Luttke, 1957
C-N stretch 870 m Ar IR Barnes, Hallam, et al., 1976
CNO bend 574 w m Ar IR Barnes, Hallam, et al., 1976
a CH3 a-stretch 2955 w Ar IR Barnes, Hallam, et al., 1976
CH3 a-deform. 1410 s Ar IR Barnes, Hallam, et al., 1976
CH3 rock 916 w m Ar IR Barnes, Hallam, et al., 1976

Additional references: Jacox, 1994, page 320; Turner and Cox, 1978

Notes

wWeak
mMedium
sStrong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Christie, Frost, et al., 1965
Christie, M.I.; Frost, J.S.; Voisey, M.A., Kinetics of some reactions of nitrosoalkanes, Trans. Faraday Soc., 1965, 61, 674-680. [all data]

Barnes, Hallam, et al., 1976
Barnes, A.J.; Hallam, H.E.; Waring, S.; Armstrong, J.R., J. Chem. Soc., 1976, Faraday Trans. 2 72, 1. [all data]

Luttke, 1957
Luttke, W., Z. Elektrochem., 1957, 61, 302. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Turner and Cox, 1978
Turner, P.H.; Cox, A.P., J. Chem. Soc., 1978, Faraday Trans. 2 74, 533. [all data]


Notes

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