Borane, chlorothioxo-
- Formula: BClS
- Molecular weight: 78.329
- CAS Registry Number: 55753-38-3
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | BS stretch | 1407.56 | gas | IR | August, Aziz, et al., 1988 Chau, Tang, et al., 1994 McNaughton and Tay-Lim, 2000 | |
| Π | 2 | Bend | 300 ± 40 | gas | MW | Kirby and Kroto, 1980 | |
| Σ+ | 3 | BCl stretch | 529.90 | gas | IR | August, Aziz, et al., 1988 Chau, Tang, et al., 1994 McNaughton and Tay-Lim, 2000 | |
Additional references: Jacox, 1994, page 85; Jacox, 1998, page 189; Jacox, 2003, page 130; Kirby, Kroto, et al., 1978; Bizzocchi, Degli Esposti, et al., 2002
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
August, Aziz, et al., 1988
August, J.A.; Aziz, S.; Kroto, H.W.; Suffolk, R.J.,
unpublished data, 1988. [all data]
Chau, Tang, et al., 1994
Chau, F.T.; Tang, Y.W.; Song, X.,
Geometries of thioborine and chlorothioboron cations,
J. Electron Spectrosc. Relat. Phenom., 1994, 70, 1, 39, https://doi.org/10.1016/0368-2048(94)02209-I
. [all data]
McNaughton and Tay-Lim, 2000
McNaughton, D.; Tay-Lim, R.,
The High-Resolution FTIR Spectrum and Equilibrium Structure of Chloro(sulphido)boron,
J. Mol. Spectrosc., 2000, 202, 1, 89, https://doi.org/10.1006/jmsp.2000.8103
. [all data]
Kirby and Kroto, 1980
Kirby, C.; Kroto, H.W.,
The microwave spectrum of the transient molecule chloro(sulphido)boron, ClB«58875»S: Substitution structure, dipole moment, quadrupole moment, and vibration-rotation analysis,
J. Mol. Spectrosc., 1980, 83, 1, 130, https://doi.org/10.1016/0022-2852(80)90316-1
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Kirby, Kroto, et al., 1978
Kirby, C.; Kroto, H.W.; Westwood, N.P.C.,
Detection of chlorothioborine, ClB=S, a new unstable triatomic molecule, by photoelectron microwave spectroscopy,
J. Am. Chem. Soc., 1978, 100, 3766. [all data]
Bizzocchi, Degli Esposti, et al., 2002
Bizzocchi, L.; Degli Esposti, C.; Puzarini, C.,
Millimeter-Wave Spectroscopy of ClBS: An Improved Evaluation of the Equilibrium Structure of Chlorothioborine,
J. Mol. Spectrosc., 2002, 216, 2, 177, https://doi.org/10.1006/jmsp.2002.8538
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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