Gallium monochloride
- Formula: ClGa
- Molecular weight: 105.176
- CAS Registry Number: 17108-85-9
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Gas phase ion energetics data
Go To: Top, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias and Joel F. Liebman
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.91 | PE | Grabandt, Mooyman, et al., 1990 | |
| 10.07 | PE | Grabandt, Mooyman, et al., 1990 | Vertical value |
Constants of diatomic molecules
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through July, 1976
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Continuous absorption at 41200 and 47600 cm-1. | ||||||||||||
| ↳Miescher and Wehrli, 1933; Levin and Winans, 1951 | ||||||||||||
| C 1Π | (40261) | [120] 1 H | C ← X R | 40139 H | ||||||||
| ↳Miescher and Wehrli, 1933; missing citation | ||||||||||||
| B 3Π1 | 29859.4 | 395.3 H | 2.5 | [0.15686] 2 | [2.1523] | B ↔ X V | 29874.03 2 Z | |||||
| ↳Miescher and Wehrli, 1933; missing citation | ||||||||||||
| A 3Π0+ | 29527.2 | 395.3 H | 2.3 3 | 0.015 | [0.15779] 4 | [2.1460] | A ↔ X V | (29541.9) (Z) | ||||
| ↳Miescher and Wehrli, 1933; missing citation | ||||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| X 1Σ+ | 0 | 365.3 5 H | 1.2 | 0.1499045 | 0.0007936 6 | 0.0000018 | (1.01E-7) 7 | 2.201690 8 | ||||
| ↳Barrett and Mandel, 1958; Tiemann, Grasshoff, et al., 1972 | ||||||||||||
Notes
| 1 | Bands with v'=1 are diffuse on account of predissociation. |
| 2 | Recalculated by Bartky, 1960 from data in Levin and Winans, 1951. |
| 3 | missing note |
| 4 | B0' - B0" redetermined from the differences between consecutive lines in the R and P branches measured by Levin and Winans, 1951. |
| 5 | ΔG(1/2) = 363.32 Bartky, 1960 from band origins Bartky, 1960. |
| 6 | missing note |
| 7 | Calculated from 4Be3/ωe2. |
| 8 | Microwave sp. 10 |
| 9 | From spectroscopic evidence concerning C 1Π, see Barrow, 1960. Good agreement with the flame photometric value of Bulewicz, Phillips, et al., 1961. |
| 10 | eqQ(69Ga) = -[92.40 - 0.68(v+1/2)] MHz, eqQ(35Cl) = -[13.20 + 0.20(v+1/2)] MHz Tiemann, Grasshoff, et al., 1972. |
References
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Grabandt, Mooyman, et al., 1990
Grabandt, O.; Mooyman, R.; De Lange, C.A.,
He(I) photoelectron spectroscopy of the gallium monohalides,
Chem. Phys., 1990, 143, 227. [all data]
Miescher and Wehrli, 1933
Miescher, E.; Wehrli, M.,
Die spektren der galliumhalogenide,
Helv. Phys. Acta, 1933, 6, 458. [all data]
Levin and Winans, 1951
Levin, F.K.; Winans, J.G.,
The absorption spectrum of GaCl,
Phys. Rev., 1951, 84, 431. [all data]
Barrett and Mandel, 1958
Barrett, A.H.; Mandel, M.,
Microwave spectra of the Tl, In, and Ga monohalides,
Phys. Rev., 1958, 109, 1572. [all data]
Tiemann, Grasshoff, et al., 1972
Tiemann, E.; Grasshoff, M.; Hoeft, J.,
Hyperfeinstruktur im Rotationsspektrum des GaCl,
Z. Naturforsch. A, 1972, 27, 753. [all data]
Bartky, 1960
Bartky, I.R.,
Recalculation of the molecular constants of Ga69Cl35,
J. Mol. Spectrosc., 1960, 5, 206. [all data]
Barrow, 1960
Barrow, R.F.,
Dissociation energies of the gaseous monohalides of boron, aluminium, gallium, indium, and thallium,
Trans. Faraday Soc., 1960, 56, 952. [all data]
Bulewicz, Phillips, et al., 1961
Bulewicz, E.M.; Phillips, L.F.; Sugden, T.M.,
Determination of dissociation constants and heats of formation of simple molecules by flame photometry. Part 8. Stabilities of the gaseous diatomic halides of certain metals,
Trans. Faraday Soc., 1961, 57, 921. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References
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