iron difluoride
- Formula: F2Fe
- Molecular weight: 93.842
- CAS Registry Number: 7789-28-8
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
View reactions leading to F2Fe+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
<2.69291 | TDEq | Borshchevskii, Boltalina, et al., 1988 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.3 ± 0.3 | EI | Kent and Margrave, 1965 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
FeF+ | 12.6 ± 0.3 | F | EI | Kent and Margrave, 1965 | RDSH |
Fe+ | 16.5 ± 0.3 | ? | EI | Kent and Margrave, 1965 | RDSH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N.,
Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions.,
J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8
. [all data]
Kent and Margrave, 1965
Kent, R.A.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. VIII. The sublimation pressure of iron(II) fluoride,
J. Am. Chem. Soc., 1965, 87, 4754. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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