Cl2SO2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 48970 ± 320 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 44860 ± 320 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 39370 ± 320 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 16540 ± 1000 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 13640 ± 320 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 7660 ± 1000 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   D?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 SO2 stretch 1170 ± 40 gas PE Chadwick, Frost, et al., 1973
2 SO2 scissors 580 ± 40 gas PE Chadwick, Frost, et al., 1973
3 SCl2 stretch 380 ± 40 gas PE Chadwick, Frost, et al., 1973
4 SCl2 scissors 200 ± 40 gas PE Chadwick, Frost, et al., 1973

State:   B?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 640 ± 40 gas PE Chadwick, Frost, et al., 1973

State:   A?

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 500 ± 40 gas PE Chadwick, Frost, et al., 1973

Additional references: Jacox, 1994, page 301

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mines, Thomas, et al., 1972
Mines, G.W.; Thomas, R.K.; Thompson, H., Photoelectron spectra of compounds containing thionyl and sulphuryl groups, Proc. R. Soc. London A:, 1972, 329, 275. [all data]

Chadwick, Frost, et al., 1973
Chadwick, D.; Frost, D.C.; Herring, F.G.; Katrib, A.; McDowell, C.A.; McLean, R.A.N., Photoelectron spectra of sulfuryl and thionyl halides, Can. J. Chem., 1973, 51, 1893. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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