F2SO+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 47120 ± 320 gas Mines, Thomas, et al., 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 SF2 stretch 705 ± 40 gas PE Mines, Thomas, et al., 1972
4 SF2 scissors 390 ± 40 gas PE Mines, Thomas, et al., 1972

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 38570 ± 320 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 34800 ± 1000 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 18960 ± 320 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 SO stretch 1180 ± 40 gas PE Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973
2 SF2 s-stretch 790 ± 40 gas PE Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973
4 SF2 scissors 350 ± 40 gas PE Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 15330 ± 500 gas Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 SO stretch 1000 T gas PE Chadwick, Frost, et al., 1973

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 FSO s-deform. 420 ± 40 gas PE Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973
3 FSO s-deform. 455.6 Ne IR Lugez, Jacox, et al., 1998

Additional references: Jacox, 1994, page 223; Jacox, 2003, page 243

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mines, Thomas, et al., 1972
Mines, G.W.; Thomas, R.K.; Thompson, H., Photoelectron spectra of compounds containing thionyl and sulphuryl groups, Proc. R. Soc. London A:, 1972, 329, 275. [all data]

Chadwick, Frost, et al., 1973
Chadwick, D.; Frost, D.C.; Herring, F.G.; Katrib, A.; McDowell, C.A.; McLean, R.A.N., Photoelectron spectra of sulfuryl and thionyl halides, Can. J. Chem., 1973, 51, 1893. [all data]

Lugez, Jacox, et al., 1998
Lugez, C.L.; Jacox, M.E.; King, R.A.; Schaefer, H.F., III, Experimental and ab initio study of the infrared spectra of ionic species derived from SF[sub 6] and SF[sub 4] and trapped in solid neon, J. Chem. Phys., 1998, 108, 23, 9639, https://doi.org/10.1063/1.476440 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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