FClO3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 67400 ± 900 gas DeKock, Lloyd, et al., 1972

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 54500 ± 120 gas DeKock, Lloyd, et al., 1972

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 33770 ± 200 gas DeKock, Lloyd, et al., 1972

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19690 ± 100 gas DeKock, Lloyd, et al., 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO3 stretch 790 ± 40 gas PE DeKock, Lloyd, et al., 1972

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 10850 ± 200 gas DeKock, Lloyd, et al., 1972

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 5930 ± 200 gas DeKock, Lloyd, et al., 1972

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 ClO3 stretch 900 ± 40 gas PE DeKock, Lloyd, et al., 1972
3 ClO3 umbrella 520 ± 40 gas PE DeKock, Lloyd, et al., 1972

Additional references: Jacox, 1994, page 300

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DeKock, Lloyd, et al., 1972
DeKock, R.L.; Lloyd, D.R.; Hillier, I.H.; Saunders, V.R., Experimental and theoretical study of the electronic structures of sulphuryl fluoride and perchloryl fluoride, Proc. R. Soc. London A:, 1972, 328, 401. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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