HCFCl2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F,G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 47360 ± 800 gas Doucet, Sauvageau, et al., 1973
Novak, Cvitas, et al., 1981

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 22830 ± 800 gas Doucet, Sauvageau, et al., 1973
Novak, Cvitas, et al., 1981

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 20570 ± 800 gas Doucet, Sauvageau, et al., 1973
Novak, Cvitas, et al., 1981
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' CCl2 stretch 610 ± 80 gas PE Novak, Cvitas, et al., 1981
FCCl deform. 400 ± 80 gas PE Novak, Cvitas, et al., 1981

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 8470 ± 800 gas Doucet, Sauvageau, et al., 1973
Novak, Cvitas, et al., 1981
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' CCl2 scissors 280 ± 80 gas PE Novak, Cvitas, et al., 1981

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 3630 ± 800 gas Doucet, Sauvageau, et al., 1973
Novak, Cvitas, et al., 1981

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 1600 ± 800 gas Doucet, Sauvageau, et al., 1973
Novak, Cvitas, et al., 1981

Additional references: Jacox, 1994, page 275

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Doucet, Sauvageau, et al., 1973
Doucet, J.; Sauvageau, P.; Sandorfy, C., Vacuum ultraviolet and photoelectron spectra of fluoro-chloro derivatives of methane, J. Chem. Phys., 1973, 58, 3708. [all data]

Novak, Cvitas, et al., 1981
Novak, I.; Cvitas, T.; Klasinc, L.; Gusten, H., J. Chem. Soc., 1981, Faraday Trans. 2 77, 2049. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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