CHCl=CF2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G,H
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 65760 ± 320 gas Potts, Benson, et al., 1987

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 49700 ± 320 gas Potts, Benson, et al., 1987

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 46470 ± 320 gas Potts, Benson, et al., 1987

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 40500 ± 320 gas Potts, Benson, et al., 1987

State:   B,C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 26380 ± 320 gas Potts, Benson, et al., 1987

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 15570 ± 320 gas Potts, Benson, et al., 1987
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1090 ± 80 gas PE Potts, Benson, et al., 1987
570 ± 80 gas PE Potts, Benson, et al., 1987

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' C=C stretch 1570 ± 80 gas PE Potts, Benson, et al., 1987
CCl stretch 930 ± 80 gas PE Potts, Benson, et al., 1987
CF2 scissors 470 ± 80 gas PE Potts, Benson, et al., 1987

Additional references: Jacox, 1994, page 340

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Potts, Benson, et al., 1987
Potts, A.W.; Benson, J.M.; Novak, I.; Svensson, W.A., Electron correlation effects in the valence shell photoelectron spectra of haloethenes, Chem. Phys., 1987, 115, 2, 253, https://doi.org/10.1016/0301-0104(87)80039-3 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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