NSF+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 46000 ± 800 gas DeKock, Lloyd, et al., 1972

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 40500 ± 320 gas Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 27350 ± 160 gas Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NS stretch 895 ± 30 gas PE Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 18030 ± 120 gas Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NS stretch 1060 ± 40 gas PE Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972
2 Bend 365 ± 40 gas PE Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972
3 SF stretch 695 ± 40 gas PE Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 14860 ± 120 gas Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 460 ± 50 gas PE Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972
3 SF stretch 820 ± 40 gas PE Cowan, Gleiter, et al., 1971
Dixon, Duxbury, et al., 1972
DeKock, Lloyd, et al., 1972

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 300 ± 50 gas PE DeKock, Lloyd, et al., 1972

Additional references: Jacox, 1994, page 94

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DeKock, Lloyd, et al., 1972
DeKock, R.L.; Lloyd, D.R.; Breeze, A.; Collins, G.A.D.; Cruickshank, D.W.J.; Lempka, H.J., Photoelectron spectroscopy and ab initio LCAO MO SCF calculations on thiazyl fluoride, Chem. Phys. Lett., 1972, 14, 525. [all data]

Cowan, Gleiter, et al., 1971
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E.; Schaublin, J., The photoelectron spectrum of thiazyl fluoride (NSF), Helv. Chim. Acta, 1971, 54, 1559. [all data]

Dixon, Duxbury, et al., 1972
Dixon, R.N.; Duxbury, G.; Fleming, G.R.; Hugo, J.M.V., The photoelectron spectrum of thiazyl fluoride, Chem. Phys. Lett., 1972, 14, 60. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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