1,3,5-C6H3ClF2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19220 ± 10 gas B-X 510 620 Maier, Marthaler, et al., 1980
To = 19095 Ne B-X 480 530 Bondybey, Vaughn, et al., 1981
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1530 ± 10 Ne AB Bondybey, Vaughn, et al., 1981
1055 ± 10 Ne AB Bondybey, Vaughn, et al., 1981
415 ± 10 Ne AB Bondybey, Vaughn, et al., 1981

Additional references: Jacox, 1994, page 434

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Marthaler, et al., 1980
Maier, J.P.; Marthaler, O.; Mohraz, M.; Shiley, R.H., (π-1) → (π-1), (π-1) emission spectra of chlorofluorobenzene cations in the gaseous phase and their lifetimes in the (0o) states, Chem. Phys., 1980, 47, 3, 295, https://doi.org/10.1016/0301-0104(80)85015-4 . [all data]

Bondybey, Vaughn, et al., 1981
Bondybey, V.E.; Vaughn, C.R.; Miller, T.A.; English, J.H.; Shiley, R.H., Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution, J. Chem. Phys., 1981, 74, 12, 6584, https://doi.org/10.1063/1.441120 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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