XeF2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 35900 ± 500 gas Brundle, Robin, et al., 1970
Brehm, Menzinger, et al., 1970
Yates, Tan, et al., 1986

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 23400 ± 500 gas Brundle, Robin, et al., 1970
Brehm, Menzinger, et al., 1970
Yates, Tan, et al., 1986

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13310 ± 500 gas Brundle, Robin, et al., 1970
Brehm, Menzinger, et al., 1970
Yates, Tan, et al., 1986

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 9920 ± 500 gas Brundle, Robin, et al., 1970
Brehm, Menzinger, et al., 1970
Yates, Tan, et al., 1986

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 XeF2 stretch 520 ± 30 gas PE Brundle, Robin, et al., 1970

Additional references: Jacox, 1994, page 117

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brundle, Robin, et al., 1970
Brundle, C.R.; Robin, M.B.; Jones, G.R., High resolution He I and He II photoelectron spectra of xenon difluoride, J. Chem. Phys., 1970, 52, 3383. [all data]

Brehm, Menzinger, et al., 1970
Brehm, B.; Menzinger, M.; Zorn, C., The photoelectron spectrum of XeF2, Can. J. Chem., 1970, 48, 3193. [all data]

Yates, Tan, et al., 1986
Yates, B.W.; Tan, K.H.; Bancroft, G.M.; Coatsworth, L.L.; Tse, J.S.; Schrobilgen, G.J., Photoelectron study of the valence level cross sections of XeF2 from 21 to 50 eV photon energy, J. Chem. Phys., 1986, 84, 7, 3603, https://doi.org/10.1063/1.450196 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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