NO2+ (structure unspecified)
- Formula: NO2+
- Molecular weight: 46.0050
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to NO2+ (ion structure unspecified)
| Precursor | AP (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| BrNO3 | 10.6 | BrO | PI | Jochims, Denzer, et al., 1992 | |
| BrNO3 | 13.2 | Br+O | PI | Jochims, Denzer, et al., 1992 | |
| CH3NO2 | 12.1 ± 0.1 | CH3 | PI | Lifshitz, Rejwan, et al., 1988 | |
| CH3NO2 | 11.97 | CH3 | PE | Ogden, Shaw, et al., 1983 | |
| CH3NO2 | 12.1 | CH3 | PIPECO | Niwa, Tajima, et al., 1981 | |
| CH3NO2 | 13. ± 0. | CH3 | EI | Collin, 1959 | |
| CH3NO3 | 12.3 | CH3O | EI | Fraser and Paul, 1968 | |
| C2H5NO3 | 12.3 | C2H5O | EI | Fraser and Paul, 1968 | |
| C2H5NO3 | 11.40 ± 0.12 | C2H5O | EI | Collin, 1962 | |
| C2H6N2O2 | 14.6 ± 0.1 | ? | EI | Gowenlock, Jones, et al., 1961 | |
| C4H9NO3 | 12.7 | C4H9O | EI | Fraser and Paul, 1968 | |
| C11H13ClO | 11.8 | C3H7O | EI | Fraser and Paul, 1968 | |
| ClNO3 | 11.07 | ClO | PI | Jochims, Denzer, et al., 1992 | |
| ClNO3 | 13.7 ± 0.1 | Cl+O | PI | Jochims, Denzer, et al., 1992 | |
| HNO3 | 11.90 | OH | PI | Jochims, Denzer, et al., 1992 | |
| N2O5 | 11.8 | NO3 | PI | Jochims, Denzer, et al., 1992 | |
| N2O5 | ~13. | NO2+O | PI | Jochims, Denzer, et al., 1992 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Jochims, Denzer, et al., 1992
Jochims, H.-W.; Denzer, W.; Baumgartel, H.; Losking, O.; Willner, H.,
Photochemical decay reactions of N2O5, HNO3, ClNO3 and BrNO3 in the energy range 10-20 eV,
Ber. Bunsen-Ges. Phys. Chem., 1992, 96, 573. [all data]
Lifshitz, Rejwan, et al., 1988
Lifshitz, C.; Rejwan, M.; Levin, I.; Peres, T.,
Unimolecular fragmentations of the nitromenthane cation,
Int. J. Mass Spectrom. Ion Processes, 1988, 84, 271. [all data]
Ogden, Shaw, et al., 1983
Ogden, I.K.; Shaw, N.; Danby, C.J.; Powis, I.,
Competing dissociation channels of nitromethane and methyl nitrite ions and the role of electronic and internal modes of excitation,
Int. J. Mass Spectrom. Ion Processes, 1983, 54, 41. [all data]
Niwa, Tajima, et al., 1981
Niwa, Y.; Tajima, S.; Tsuchiya, T.,
Fragmentation of energy-selected nitromethane ions,
Int. J. Mass Spectrom. Ion Processes, 1981, 40, 287. [all data]
Collin, 1959
Collin, J.,
Ionization and dissociation of molecules by monoenergetic electrons. III. On the existence of a bent excited state of NO2+,
J. Chem. Phys., 1959, 30, 1621. [all data]
Fraser and Paul, 1968
Fraser, R.T.M.; Paul, N.C.,
The mass spectrometry of nitrate esters and related compounds. Part I,
J. Chem. Soc. B, 1968, 659. [all data]
Collin, 1962
Collin, J.E.,
Ionization potential of NO2,
Nature, 1962, 196, 373. [all data]
Gowenlock, Jones, et al., 1961
Gowenlock, B.G.; Jones, P.P.; Majer, J.R.,
Bond dissociation energies in some molecules containing alkyl substituted CH3, NH2, and OH,
J. Chem. Soc. Faraday Trans., 1961, 57, 23. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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