H3Si+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to H3Si+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
CH6Si12.5?EIBradshaw, Moyes, et al., 1976 
CH6Si12.8 ± 0.1CH3EISteele, Nichols, et al., 1962 
C2H8Si12.8 ± 0.2C2H5EISteele, Nichols, et al., 1962 
C3H10Si13.1 ± 0.2?EISteele, Nichols, et al., 1962 
C3H10Si14.3 ± 0.5?EIHobrock and Kiser, 1962Personal communication from R.M. Reese and V.H. Dibeler
C4H12Si13.7 ± 0.2?EISteele, Nichols, et al., 1962 
C4H12Si16.5?EIdeRidder and Dijkstra, 1967 
C8H20Si20.6?EIdeRidder and Dijkstra, 1967 
H6GeSi12.01 ± 0.09?EISaalfeld and Svec, 1966 
H4Si12.10HDERShin, Corderman, et al., 1990 
H4Si≤12.086 ± 0.020HPIBerkowitz, Greene, et al., 1987 
H4Si12.10 ± 0.05HPIBorlin, Heinis, et al., 1986 
H4Si12.23 ± 0.02HPIDing, Cassidy, et al., 1985 
H4Si12.2 ± 0.4HEIChatham, Hils, et al., 1984 
H4Si12.3 ± 0.1HEIPotzinger, Ritter, et al., 1975 
H4Si12.2HEIMorrison and Traeger, 1973 
H4Si12.30 ± 0.03HEIPotzinger and Lampe, 1969 
H4Si11.81 ± 0.09HEISaalfeld and Svec, 1966 
H4Si11.8 ± 0.2HEISaalfeld and Svec, 1963 
H4Si12.40 ± 0.02HEISteele, Nichols, et al., 1962 
H5PSi11.5 ± 0.2?EISaalfeld and Svec, 1964 
H6Si2≤11.72 ± 0.02?PIRuscic and Berkowitz, 1991T = 0K
H6Si211. ± 2.?EIChatham, Hils, et al., 1984 
H6Si211.8 ± 0.1SiH3EIPotzinger, Ritter, et al., 1975 
H6Si211.95 ± 0.15SiH3EIPotzinger and Lampe, 1969 
H6Si211.31 ± 0.12SiH3EISaalfeld and Svec, 1966 
H6Si211.3 ± 0.2SiH3EISaalfeld and Svec, 1964 
H6Si211.85 ± 0.05SiH3EISteele and Stone, 1962 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bradshaw, Moyes, et al., 1976
Bradshaw, D.I.; Moyes, R.B.; Wells, P.B., Mass spectra of some deuterium-labelled methylsilanes the analysis of mixtures, Can. J. Chem., 1976, 54, 599. [all data]

Steele, Nichols, et al., 1962
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., The determination of silicon-carbon and silicon-hydrogen bond dissociation energies by electron impact, J. Am. Chem. Soc., 1962, 84, 4441. [all data]

Hobrock and Kiser, 1962
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of tetramethylgermanium, trimethylsilane, and dimethylmercury, J. Phys. Chem., 1962, 66, 155. [all data]

deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G., Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead, Rec. Trav. Chim., 1967, 86, 737. [all data]

Saalfeld and Svec, 1966
Saalfeld, F.E.; Svec, H.J., Mass spectra of volatile hydrides. IV. Silylgermane, J. Phys. Chem., 1966, 70, 1753. [all data]

Shin, Corderman, et al., 1990
Shin, S.K.; Corderman, R.R.; Beauchamp, J.L., Photoionization mass spectrometric studies of the methylsilanes Si(CH3)nH4-n (n = 0-3), Int. J. Mass Spectrom. Ion Processes, 1990, 101, 257. [all data]

Berkowitz, Greene, et al., 1987
Berkowitz, J.; Greene, J.P.; Cho, H.; Ruscic, B., Photoionization mass spectrometric studies of SiHn (n=1-4), J. Chem. Phys., 1987, 86, 1235. [all data]

Borlin, Heinis, et al., 1986
Borlin, K.; Heinis, T.; Jungen, M., Photoionization mass spectrometry of silane, Chem. Phys., 1986, 103, 93. [all data]

Ding, Cassidy, et al., 1985
Ding, A.; Cassidy, R.; Cordis, L.; Lampe, F., The photoionization spectra of effusing and supersonic molecular beams of Mmnosilane, J. Chem. Phys., 1985, 83, 3426. [all data]

Chatham, Hils, et al., 1984
Chatham, H.; Hils, D.; Robertson, R.; Gallagher, A., Total and partial electron collisional ionization cross sections for CH4, C2H6, SiH4, and Si2H6, J. Chem. Phys., 1984, 81, 1770. [all data]

Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J., Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen, Z. Naturforsch. A:, 1975, 30, 347. [all data]

Morrison and Traeger, 1973
Morrison, J.D.; Traeger, J.C., Ionization and dissociation by electron impact. III. CH4 and SiH4, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 289. [all data]

Potzinger and Lampe, 1969
Potzinger, P.; Lampe, F.W., An electron impact study of ionization and dissociation of monosilane and disilane, J. Phys. Chem., 1969, 73, 3912. [all data]

Saalfeld and Svec, 1963
Saalfeld, F.E.; Svec, H.J., The mass spectra of volatile hydrides. I. The monoelemental hydrides of the group IVB and VB elements, Inorg. Chem., 1963, 2, 46. [all data]

Saalfeld and Svec, 1964
Saalfeld, F.E.; Svec, H.J., Mass spectra of volatile hydrides. III. Silylphosphine, Inorg. Chem., 1964, 3, 1442. [all data]

Ruscic and Berkowitz, 1991
Ruscic, B.; Berkowitz, J., Photoionization mass spectrometric study of Si2H6, J. Chem. Phys., 1991, 95, 2407. [all data]

Steele and Stone, 1962
Steele, W.C.; Stone, F.G.A., Silicon-silicon bond dissociation energies in disilane and hexachlorodisilane, J. Am. Chem. Soc., 1962, 84, 3599. [all data]


Notes

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