CH4S+ (structure unspecified)
- Formula: CH4S+
- Molecular weight: 48.107
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to CH4S+ (ion structure unspecified)
Precursor | AP (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C2H6OS | 10.42 ± 0.05 | CH2O | EI | Holmes, Lossing, et al., 1983 | |
C2H6S2 | 10.4 ± 0.1 | CH2S | PIPECO | Butler, Baer, et al., 1983 | T = 298K |
C2H6S2 | 9.72 ± 0.09 | ? | EI | Cullen, Frost, et al., 1970 | |
C3H8S | 10.4 ± 0.1 | ? | EI | Keyes and Harrson, 1968 | |
C4H8S | 11.5 ± 0.2 | ? | EI | Hobrock and Kiser, 1963 | |
C4H10S | 12.0 ± 0.2 | ? | EI | Hobrock and Kiser, 1963 | |
C4H10S | 10.5 ± 0.1 | ? | EI | Keyes and Harrson, 1968 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Holmes, Lossing, et al., 1983
Holmes, J.L.; Lossing, F.P.; Terlouw, J.K.; Burgers, P.C.,
Novel gas-phase ions. The radical cations [CH2XH]+. (X = F, Cl, Br, I, OH, NH2, SH) and [CH2CH2NH3]+.,
Can. J. Chem., 1983, 61, 2305. [all data]
Butler, Baer, et al., 1983
Butler, J.J.; Baer, T.; Evans, S.A., Jr.,
Energetics and structures of organosulfur ions: CH3SSCH3+, CH3SS+, C2H5S+, and CH2SH+,
J. Am. Chem. Soc., 1983, 105, 3451. [all data]
Cullen, Frost, et al., 1970
Cullen, W.R.; Frost, D.C.; Pun, M.T.,
Mass spectra, appearance potentials, heats of formation, and bond energies of some alkyl and perfluoroalkyl sulfides,
Inorg. Chem., 1970, 9, 1976. [all data]
Keyes and Harrson, 1968
Keyes, B.G.; Harrson, A.G.,
The fragmentation of aliphatic sulfur compounds by electron impact,
J. Am. Chem. Soc., 1968, 90, 5671. [all data]
Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W.,
Electron impact investigations of sulfur compounds. II. 3-Methyl-2-thiabutane, 4-thia-1-pentene, and 3,4-dithiahexane,
J. Phys. Chem., 1963, 67, 648. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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