CH4N+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to CH4N+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
CH5N10.18HEILossing, Lam, et al., 1981 
CH5N10.70HEILoudon and Webb, 1977 
CH5N10.55HEILoudon and Webb, 1977 
CH5N10.82 ± 0.15HEICollin and Franskin, 1966 
CH5N10.3 ± 0.1HEITaft, Martin, et al., 1965 
C2H4D3N9.8 ± 0.1CD3EICollin, Franskin, et al., 1967 
C2H5D2N10.0CHD2EICollin, Franskin, et al., 1967 
C2H5NO11.65?EILoudon and Webb, 1977 
C2H5NO210.27 ± 0.05?EIZaretskii, Sadovskaya, et al., 1971 
C2H5NO210.23 ± 0.09?EISvec and Junk, 1967 
C2H5NO210.1 ± 0.2?EIJunk and Svec, 1963 
C2H6N2O11.65?EILoudon and Webb, 1977 
C2H6N2S11.10?EILoudon and Webb, 1977 
C2H7N10.80?EILoudon and Webb, 1977 
C2H7N9.69CH3EILossing, Lam, et al., 1981 
C2H7N10.2 ± 0.1CH3EICollin, Franskin, et al., 1967 
C2H7N9.71CH3PIChupka, 1959 
C2H7NO9.49 ± 0.05CH2OHEIHolmes and Lossing, 1984 
C2H7NO9.49CH2OHEILossing, Lam, et al., 1981 
C2H8N29.56CH2NH2EIBurkey, Castelhano, et al., 1983 
C3H7N12.3 ± 0.2?EIGallegos and Kiser, 1962 
C3H7NO11.50?EILoudon and Webb, 1977 
C3H8N2O11.45?EILoudon and Webb, 1977 
C3H8N2S11.25?EILoudon and Webb, 1977 
C3H9N9.56C2H5EILossing, Lam, et al., 1981 
C3H9N9.54C2H5PIChupka, 1959 
C3H9NO9.52 ± 0.05CH3OCH2EIHolmes and Lossing, 1984 
C4H9N12.7 ± 0.2?EIGallegos and Kiser, 1962 
C4H10N2O11.45?EILoudon and Webb, 1977 
C4H10N2S11.60?EILoudon and Webb, 1977 
C4H11N9.621-C3H7EIHolmes, Lossing, et al., 1988 
C4H11N13.10 ± 0.10C2H4+CH3EICollin and Franskin, 1966, 2 
C4H11N9.522-C3H7EIHolmes, Lossing, et al., 1988 
C4H11NO29.46 ± 0.05(CH30)2CHEIHolmes and Lossing, 1984 
C5H13N9.611-C4H9EIHolmes, Lossing, et al., 1988 
C5H13N9.47(CH3)3CEIHolmes, Lossing, et al., 1988 
C5H13N9.44 ± 0.05(CH3)3CEIHolmes and Lossing, 1984 
C5H13N9.572-C4H9EIHolmes, Lossing, et al., 1988 
C6H15N9.67(CH3)3CCH2EIHolmes, Lossing, et al., 1988 
C7H9N10.08 ± 0.05C6H5EIHolmes and Lossing, 1984 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lossing, Lam, et al., 1981
Lossing, F.P.; Lam, Y.-T.; Maccoll, A., Gas phase heats of formation of alkyl immonium ions, Can. J. Chem., 1981, 59, 2228. [all data]

Loudon and Webb, 1977
Loudon, A.G.; Webb, K.S., The nature of the [C2H6N]+ and [CH4N]+ ions formed by electron impact on methylated formamides, acetamides, ureas, thioureas and hexamethylphosphoramide, Org. Mass Spectrom., 1977, 12, 283. [all data]

Collin and Franskin, 1966
Collin, J.E.; Franskin, M.J., Ionisation, dissociation et rearrangements intramoleculaires dans les amines aliphatiques par impact electronique. Cas de la methylamine et de la methylamine-Nd2, Bull. Soc. Roy. Sci. Liege, 1966, 35, 267. [all data]

Taft, Martin, et al., 1965
Taft, R.W.; Martin, R.H.; Lampe, F.W., Stabilization energies of substituted methyl cations. The effect of strong demand on the resonance order, J. Am. Chem. Soc., 1965, 87, 2490. [all data]

Collin, Franskin, et al., 1967
Collin, J.E.; Franskin, M.J.; Hyatt, D., Etude par spectrometrie de masse des mechanismes de dissociation dans l'ethylamine et ses homologues deuteres, Bull. Soc. Roy. Sci. Liege, 1967, 36, 318. [all data]

Zaretskii, Sadovskaya, et al., 1971
Zaretskii, V.I.; Sadovskaya, V.L.; Wulfson, N.S.; Sizoy, V.F.; Merimson, V.G., Mass spectrometry of steroid systems-XXI. Appearance and ionization potentials for the stereoisomers of the D-homoestrane series, Org. Mass Spectrom., 1971, 5, 1179. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Electron-impact studies of substituted alkanes, J. Am. Chem. Soc., 1967, 89, 790. [all data]

Junk and Svec, 1963
Junk, G.; Svec, H., The mass spectra of the α-amino acids, J. Am. Chem. Soc., 1963, 85, 839. [all data]

Chupka, 1959
Chupka, W.A., Effect of unimolecular decay kinetics on the interpretation of appearance potentials, J. Chem. Phys., 1959, 30, 191. [all data]

Holmes and Lossing, 1984
Holmes, J.L.; Lossing, F.P., Heats of formation of organic radicals from appearance energies, Int. J. Mass Spectrom. Ion Processes, 1984, 58, 113. [all data]

Burkey, Castelhano, et al., 1983
Burkey, T.J.; Castelhano, A.L.; Griller, D.; Lossing, F.P., Heats of formation and ionization potentials of some α-aminoalkyl radicals, J. Am. Chem. Soc., 1983, 105, 4701. [all data]

Gallegos and Kiser, 1962
Gallegos, E.J.; Kiser, R.W., Electron impact spectroscopy of the four- and five-membered, saturated heterocyclic compounds containing nitrogen, oxygen and sulfur, J. Phys. Chem., 1962, 66, 136. [all data]

Holmes, Lossing, et al., 1988
Holmes, J.L.; Lossing, F.P.; Maccoll, A., Heats of formation of alkyl radicals from appearance energies, J. Am. Chem. Soc., 1988, 110, 7339. [all data]

Collin and Franskin, 1966, 2
Collin, J.E.; Franskin, M.J., Ionisation, dissociation et rearrangements intramoleculaires dans les amines aliphatiques soumises a l'impact electronique. Cas de la diethylamine et de la diethylamine-Nd, Bull. Soc. Roy. Sci. Liege, 1966, 35, 285. [all data]


Notes

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