CH3S2+ (structure unspecified)
- Formula: CH3S2+
- Molecular weight: 79.164
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to CH3S2+ (ion structure unspecified)
Precursor | AP (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C2H3F3S2 | 11.29 ± 0.20 | ? | EI | Cullen, Frost, et al., 1970 | |
C2H6S2 | 10.15 ± 0.10 | CH3 | PIPECO | Butler, Baer, et al., 1983 | T = 298K |
C2H6S2 | 11.45 | CH3 | EI | Gowenlock, Kay, et al., 1963 | |
C2H6S2 | 11.07 | CH3 | PI | Ma, Liao, et al., 1994 | Ion is CH2SSH+ |
C2H6S3 | 12.3 ± 0.2 | ? | EI | Hobrock and Kiser, 1963 | |
C4H10S2 | 13.8 ± 0.3 | ? | EI | Gal'perin, Bogolyubov, et al., 1969 | |
C5H12S2 | 9.1 ± 0.8 | (CH3)3C | EI | Hawari, Griller, et al., 1986 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cullen, Frost, et al., 1970
Cullen, W.R.; Frost, D.C.; Pun, M.T.,
Mass spectra, appearance potentials, heats of formation, and bond energies of some alkyl and perfluoroalkyl sulfides,
Inorg. Chem., 1970, 9, 1976. [all data]
Butler, Baer, et al., 1983
Butler, J.J.; Baer, T.; Evans, S.A., Jr.,
Energetics and structures of organosulfur ions: CH3SSCH3+, CH3SS+, C2H5S+, and CH2SH+,
J. Am. Chem. Soc., 1983, 105, 3451. [all data]
Gowenlock, Kay, et al., 1963
Gowenlock, B.G.; Kay, J.; Majer, J.R.,
Electron impact studies of some sulphides and disulphides,
J. Chem. Soc. Faraday Trans., 1963, 59, 2463. [all data]
Ma, Liao, et al., 1994
Ma, Z.-X.; Liao, C.L.; Ng, C.Y.; Cheung, Y.-S.; Li, W.-K.; Baer, T.,
Experimental and theoretical studies of isomeric CH3S2 and CH3S2+,
J. Chem. Phys., 1994, 100, 4870. [all data]
Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W.,
Electron impact investigations of sulfur compounds. III. 2-Thiapropane, 3-thiapentane, and 2,3,4-trithiapentane,
J. Phys. Chem., 1963, 67, 1283. [all data]
Gal'perin, Bogolyubov, et al., 1969
Gal'perin, Ya.V.; Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A.,
Organic derivatives of elements of groups V and VI. VI. Mass spectra of compounds with S-S bonds,
Zh. Obshch. Khim., 1969, 39, 1599, In original 1567. [all data]
Hawari, Griller, et al., 1986
Hawari, J.A.; Griller, D.; Lossing, F.P.,
Thermochemistry of perthiyl radicals,
J. Am. Chem. Soc., 1986, 108, 3273. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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