CH2Cl+ (structure unspecified)
- Formula: CH2Cl+
- Molecular weight: 49.479
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to CH2Cl+ (ion structure unspecified)
Precursor | AP (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CH2BrCl | 11.6 ± 0.1 | Br | EI | Harrison and Shannon, 1962 | |
CH2Cl2 | 12.10 | Cl | EI | Holmes, Lossing, et al., 1988 | |
CH2Cl2 | 12.14 ± 0.02 | Cl | PI | Werner, Tsai, et al., 1974 | |
CH2Cl2 | 12.15 | Cl | EI | Lossing, 1972 | |
CH2Cl2 | 12.1 ± 0.1 | Cl | EI | Harrison and Shannon, 1962 | |
CH2Cl2 | 12.89 ± 0.03 | Cl | EI | Reed and Snedden, 1956 | |
CH3Cl | 12.96 | H | EI | Lossing, 1972 | |
CH3Cl | 12.98 ± 0.07 | H | EI | Martin, Lampe, et al., 1966 | |
C2H4Cl2 | 12.5 ± 0.1 | CH2Cl | EI | Harrison and Shannon, 1962 | |
C2H5Cl | 13.2 ± 0.2 | CH3 | EI | Harrison and Shannon, 1962 | |
C2H5Cl | 13.6 ± 0.2 | CH3 | EI | Irsa, 1957 | |
C3H3ClN2O | 12.2 ± 0.1 | ? | EI | Foffani, Pignataro, et al., 1963 | |
C3H5ClO | 12.5 ± 0.1 | ? | EI | Wada and Kiser, 1962 | |
C3H5ClO | 13.8 ± 0.07 | ? | EI | Foffani, Pignataro, et al., 1963 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harrison and Shannon, 1962
Harrison, A.G.; Shannon, T.W.,
An electron impact study of chloromethyl and dichloromethyl derivatives,
Can. J. Chem., 1962, 40, 1730. [all data]
Holmes, Lossing, et al., 1988
Holmes, J.L.; Lossing, F.P.; McFarlane, R.A.,
Stabilization energy and positional effects in halogen-substituted alkyl ions.,
Int. J. Mass Spectrom. Ion Phys., 1988, 86, 209. [all data]
Werner, Tsai, et al., 1974
Werner, A.S.; Tsai, B.P.; Baer, T.,
Photoionization study of the ionization potentials fragmentation paths of the chlorinated methanes carbon tetrabromide,
J. Chem. Phys., 1974, 60, 3650. [all data]
Lossing, 1972
Lossing, F.P.,
Free radicals by mass spectrometry. XLIV. Ionization potentials bond dissociation energies for chloro-and fluoromethyl radicals,
Bull. Soc. Chim. Belg., 1972, 81, 125. [all data]
Reed and Snedden, 1956
Reed, R.I.; Snedden, W.,
Studies in electron impact methods. Part 6.-The formation of the methine and carbon ions,
J. Chem. Soc. Faraday Trans., 1956, 55, 876. [all data]
Martin, Lampe, et al., 1966
Martin, R.H.; Lampe, F.W.; Taft, R.W.,
An electron-impact study of ionization and dissociation in methoxy- and halogen- substituted methanes,
J. Am. Chem. Soc., 1966, 88, 1353. [all data]
Irsa, 1957
Irsa, A.P.,
Electron impact studies on C2H5Cl, C2H5Br, and C2H5I,
J. Chem. Phys., 1957, 26, 18. [all data]
Foffani, Pignataro, et al., 1963
Foffani, A.; Pignataro, S.; Cantone, B.; Grasso, F.,
Mass spectra of diazocompounds. I. Diazocarbonyl compounds,
Nuovo Cimento, 1963, 29, 918. [all data]
Wada and Kiser, 1962
Wada, Y.; Kiser, R.W.,
Electron impact spectroscopy of some substituted oxiranes,
J. Phys. Chem., 1962, 66, 1652. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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