CCl3+ (structure unspecified)
- Formula: CCl3+
- Molecular weight: 118.369
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to CCl3+ (ion structure unspecified)
Precursor | AP (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CBrCl3 | 10.9 ± 0.1 | Br | EI | Farmer, Henderson, et al., 1956 | |
CCl3F | 13.50 | F | PI | Jochims, Lohr, et al., 1976 | |
CCl3F | 13.25 ± 0.04 | F | PI | Ajello, Huntress, et al., 1976 | |
CCl3F | 12.77 ± 0.15 | F | EI | Curran, 1961 | |
CCl4 | 11. ± 1. | Cl | PI | Burton, Chan, et al., 1994 | |
CCl4 | 11.28 ± 0.03 | Cl | PI | Werner, Tsai, et al., 1974 | |
CCl4 | 11.37 | Cl | EI | Lossing, 1972 | |
CCl4 | 11.65 ± 0.10 | Cl | EI | Fox and Curran, 1961 | |
CCl4 | 11.90 ± 0.07 | Cl | EI | Reed and Snedden, 1958 | |
CCl4 | 11.7 ± 0.1 | Cl | EI | Farmer, Henderson, et al., 1956 | |
CCl4 | 12.2 ± 0.2 | Cl | EI | Baker and Tate, 1938 | |
CCl4Hg | 10.1 ± 0.08 | ? | EI | Ujszaszy, Tamas, et al., 1980 | |
CHCl3 | 11.70 ± 0.09 | H | EI | Martin, Lampe, et al., 1966 | |
C2Cl4O | 11.06 | COCl | EI | Hop, Holmes, et al., 1988 | |
C2HCl5 | 11.5 ± 0.1 | CHCl2 | EI | Harrison and Shannon, 1962 | |
C2H3Cl3 | 11.78 | CH3 | EI | Hop, Holmes, et al., 1988 | |
C3Cl6O | 11.75 | ? | EI | Majer, Olavesen, et al., 1971 | |
C3HCl3N2O | 11.0 | ? | EI | Foffani, Pignataro, et al., 1963 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Farmer, Henderson, et al., 1956
Farmer, J.B.; Henderson, I.H.S.; Lossing, F.P.; Marsden, D.G.H.,
Free radicals by mass spectrometry. IX. Ionization potentials of CF3 and CCl3 radicals and bond dissociation energies in some derivatives,
J. Chem. Phys., 1956, 24, 348. [all data]
Jochims, Lohr, et al., 1976
Jochims, H.-W.; Lohr, W.; Baumgartel, H.,
Photoreactions of small organic molecules V. Absorption-, photoion- and resonancephotoelectron-spectra of CF3Cl, CF2Cl2, CFCl3 in the energy range 10-25 eV,
Ber. Bunsen-Ges. Phys. Chem., 1976, 80, 130. [all data]
Ajello, Huntress, et al., 1976
Ajello, J.M.; Huntress, W.T., Jr.; Rayermann, P.,
A photoionization mass spectrometer study of CFCl3, CF2Cl2 and CF3Cl,
J. Chem. Phys., 1976, 64, 4746. [all data]
Curran, 1961
Curran, R.K.,
Positive and negative ion formation in CCl3F,
J. Chem. Phys., 1961, 34, 2007. [all data]
Burton, Chan, et al., 1994
Burton, G.R.; Chan, W.F.; Cooper, G.; Brion, C.E.,
Valence- and inner-shell (Cl 2p, 2s; C1s) photoabsorption and photoionization of carbon tetrachloride. Absolute oscillator strengths (5-400 eV) and dipole-induced breakdown pathways,
Chem. Phys., 1994, 181, 147. [all data]
Werner, Tsai, et al., 1974
Werner, A.S.; Tsai, B.P.; Baer, T.,
Photoionization study of the ionization potentials fragmentation paths of the chlorinated methanes carbon tetrabromide,
J. Chem. Phys., 1974, 60, 3650. [all data]
Lossing, 1972
Lossing, F.P.,
Free radicals by mass spectrometry. XLIV. Ionization potentials bond dissociation energies for chloro-and fluoromethyl radicals,
Bull. Soc. Chim. Belg., 1972, 81, 125. [all data]
Fox and Curran, 1961
Fox, R.E.; Curran, R.K.,
Ionization processes in CCl4 and SF6 by electron beams,
J. Chem. Phys., 1961, 34, 1595. [all data]
Reed and Snedden, 1958
Reed, R.I.; Snedden, W.,
Studies in electron impact methods. Part 2. The latent heat of sublimation of carbon,
J. Chem. Soc. Faraday Trans., 1958, 54, 301. [all data]
Baker and Tate, 1938
Baker, R.F.; Tate, J.T.,
Ionization and dissociation by electron impact in CCl2F2 and in CCl4 vapor,
Phys. Rev., 1938, 53, 683. [all data]
Ujszaszy, Tamas, et al., 1980
Ujszaszy, K.; Tamas, J.; Kagramanov, N.D.; Maltsev, A.K.; Nefedov, O.M.,
Mass spectrometric study of reactive intermediates formed by vacuum pyrolysis of RHgCCl3 compounds,
J. Anal. Appl. Pyrolysis, 1980, 2, 231. [all data]
Martin, Lampe, et al., 1966
Martin, R.H.; Lampe, F.W.; Taft, R.W.,
An electron-impact study of ionization and dissociation in methoxy- and halogen- substituted methanes,
J. Am. Chem. Soc., 1966, 88, 1353. [all data]
Hop, Holmes, et al., 1988
Hop, C.E.C.A.; Holmes, J.L.; Lossing, F.P.; Terlouw, J.K.,
The stability of [CCl4]+, [Cl2C-Cl-Cl]+, their dications, and neutral counterparts,
Int. J. Mass Spectrom. Ion Processes, 1988, 83, 285. [all data]
Harrison and Shannon, 1962
Harrison, A.G.; Shannon, T.W.,
An electron impact study of chloromethyl and dichloromethyl derivatives,
Can. J. Chem., 1962, 40, 1730. [all data]
Majer, Olavesen, et al., 1971
Majer, J.R.; Olavesen, C.; Robb, J.C.,
Wavelength effect in the photolysis of halogenated ketones,
J. Chem. Soc. B, 1971, 48. [all data]
Foffani, Pignataro, et al., 1963
Foffani, A.; Pignataro, S.; Cantone, B.; Grasso, F.,
Mass spectra of diazocompounds. I. Diazocarbonyl compounds,
Nuovo Cimento, 1963, 29, 918. [all data]
Notes
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