CCl2+ (structure unspecified)
- Formula: CCl2+
- Molecular weight: 82.916
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to CCl2+ (ion structure unspecified)
Precursor | AP (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CCl3F | 17.0 | FCl | PI | Jochims, Lohr, et al., 1976 | |
CCl3F | 17.12 ± 0.04 | Cl+F | PI | Ajello, Huntress, et al., 1976 | |
CCl4 | 16. ± 1. | 2Cl | PI | Burton, Chan, et al., 1994 | |
CCl4 | 14. ± 1. | Cl2 | PI | Burton, Chan, et al., 1994 | |
CCl4 | 15.4 | ? | EI | Shapiro and Lossing, 1968 | |
CCl4 | 16.0 ± 0.2 | 2Cl | EI | Baker and Tate, 1938 | |
CCl4Hg | >10.39 ± 0.06 | ? | EI | Ujszaszy, Tamas, et al., 1980 | |
CHCl3 | 12.2 | ? | EI | Shapiro and Lossing, 1968 | |
C2Cl2F2 | 13.8 ± 0.1 | CF2 | EI | Syrvatka, Gil'burd, et al., 1972 | |
C2Cl4 | 14.7 | ? | EI | Shapiro and Lossing, 1968 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Jochims, Lohr, et al., 1976
Jochims, H.-W.; Lohr, W.; Baumgartel, H.,
Photoreactions of small organic molecules V. Absorption-, photoion- and resonancephotoelectron-spectra of CF3Cl, CF2Cl2, CFCl3 in the energy range 10-25 eV,
Ber. Bunsen-Ges. Phys. Chem., 1976, 80, 130. [all data]
Ajello, Huntress, et al., 1976
Ajello, J.M.; Huntress, W.T., Jr.; Rayermann, P.,
A photoionization mass spectrometer study of CFCl3, CF2Cl2 and CF3Cl,
J. Chem. Phys., 1976, 64, 4746. [all data]
Burton, Chan, et al., 1994
Burton, G.R.; Chan, W.F.; Cooper, G.; Brion, C.E.,
Valence- and inner-shell (Cl 2p, 2s; C1s) photoabsorption and photoionization of carbon tetrachloride. Absolute oscillator strengths (5-400 eV) and dipole-induced breakdown pathways,
Chem. Phys., 1994, 181, 147. [all data]
Shapiro and Lossing, 1968
Shapiro, J.S.; Lossing, F.P.,
Free radicals by mass spectrometry. XXXVII. The ionization potential and heat of formation of dichlorocarbene,
J. Phys. Chem., 1968, 72, 1552. [all data]
Baker and Tate, 1938
Baker, R.F.; Tate, J.T.,
Ionization and dissociation by electron impact in CCl2F2 and in CCl4 vapor,
Phys. Rev., 1938, 53, 683. [all data]
Ujszaszy, Tamas, et al., 1980
Ujszaszy, K.; Tamas, J.; Kagramanov, N.D.; Maltsev, A.K.; Nefedov, O.M.,
Mass spectrometric study of reactive intermediates formed by vacuum pyrolysis of RHgCCl3 compounds,
J. Anal. Appl. Pyrolysis, 1980, 2, 231. [all data]
Syrvatka, Gil'burd, et al., 1972
Syrvatka, B.G.; Gil'burd, M.M.; Bel'ferman, A.L.,
Mass spectrometric study of chlorofluoro-substituted ethylenes,
J. Org. Chem. USSR, 1972, 8, 1587, In original 1553. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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