C3H9Si+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to C3H9Si+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
C3H9BrSi10.51 ± 0.01BrPIPECOSzepes and Baer, 1984T = 298K
C3H9BrSi10.70 ± 0.01BrPIPECOSzepes and Baer, 1984T = 0K
C3H9BrSi10.70 ± 0.01BrPIPECOSzepes and Baer, 1984, 2 
C3H9BrSi10.5 ± 0.1BrEIBand, Davidson, et al., Commun. 1967 
C3H9BrSi10.69 ± 0.06BrEIHess, Lampe, et al., 1965 
C3H9ClSi11.6 ± 0.1ClEIPotzinger, Ritter, et al., 1975 
C3H9ClSi10.9 ± 0.1ClEIBand, Davidson, et al., Commun. 1967 
C3H9ClSi11.5 ± 0.2ClEIConnor, Finney, et al., 1966 
C3H9ClSi12.40 ± 0.06ClEIHess, Lampe, et al., 1965 
C3H9ClSi12.42 ± 0.03ClEIHess, Lampe, et al., 1964 
C3H9FSi11.7 ± 0.5F-?EIHess, Lampe, et al., 1965 
C3H9ISi9.87 ± 0.01IPIPECOSzepes and Baer, 1984T = 0K
C3H9ISi9.68 ± 0.01IPIPECOSzepes and Baer, 1984T = 298K
C3H9ISi9.87 ± 0.01IPIPECOSzepes and Baer, 1984, 2T = 0K
C3H9ISi10.1 ± 0.1IEIBand, Davidson, et al., Commun. 1967 
C3H10Si10.24 ± 0.05HPIShin, Corderman, et al., 1990 
C3H10Si10.5 ± 0.1HEIPotzinger, Ritter, et al., 1975 
C3H10Si10.52 ± 0.05HEIPotzinger and Lampe, 1970 
C3H10Si10.6 ± 0.1HEIBand, Davidson, et al., Commun. 1967 
C3H10Si10.7 ± 0.1HEIConnor, Finney, et al., 1966 
C3H10Si10.78 ± 0.07HEIHess, Lampe, et al., 1964 
C3H12Si29.7 ± 0.1SiH3EIPotzinger, Ritter, et al., 1975 
C4H12OSi12.43 ± 0.18?EIHess, Lampe, et al., 1965 
C4H12Si10.09 ± 0.01CH3PIPECOSzepes and Baer, 1984T = 298K
C4H12Si10.28 ± 0.01CH3PIPECOSzepes and Baer, 1984T = 0K
C4H12Si10.28 ± 0.01CH3PIPECOSzepes and Baer, 1984, 2T = 0K
C4H12Si10.03 ± 0.04CH3PIMurphy and Beauchamp, 1977 
C4H12Si10.3 ± 0.1CH3EIPotzinger, Ritter, et al., 1975 
C4H12Si10.63 ± 0.05CH3EIMacLean and Sacher, 1974 
C4H12Si10.53 ± 0.20CH3EILappert, Pedley, et al., 1971 
C4H12Si10.25 ± 0.05CH3EIPotzinger and Lampe, 1970 
C4H12Si10.09 ± 0.02CH3PIDistefano, 1970 
C4H12Si10.53 ± 0.20CH3EILappert, Simpson, et al., 1969 
C4H12Si10.4 ± 0.1CH3EIBand, Davidson, et al., Commun. 1967 
C4H12Si10.5 ± 0.1CH3EIConnor, Finney, et al., 1966 
C4H12Si10.63 ± 0.13CH3EIHess, Lampe, et al., 1964 
C4H14Si210.1 ± 0.1CH3SiH2EIPotzinger, Ritter, et al., 1975 
C5H12Si11.C2H3EISmolinsky and Vasile, 1973 
C5H14Si10.0 ± 0.1C2H5EIPotzinger, Ritter, et al., 1975 
C5H14Si10.34 ± 0.11?EIConnor, Finney, et al., 1966 
C5H14Si10.53 ± 0.09?EIHess, Lampe, et al., 1964 
C5H16Si210.2 ± 0.1(CH3)2SiHEIPotzinger, Ritter, et al., 1975 
C6H16Si10.56 ± 0.16?EIHess, Lampe, et al., 1964 
C6H17NSi9.76C3H8NPILoguinov, Takhistov, et al., 1981 
C6H17NSi9.76C3H8NPIAkopyan, Vilesov, et al., 1975 
C6H18GeSi10.19 ± 0.12(CH3)3GeEILappert, Pedley, et al., 1971 
C6H18GeSi10.19 ± 0.12?EILappert, Simpson, et al., 1969 
C6H18HgSi28.6 ± 0.1?EIConnor, Finney, et al., 1966 
C6H18OSi215.4 ± 0.2?EIBorossay, Csakvari, et al., 1971 
C6H18OSi215.36 ± 0.13?EIHess, Lampe, et al., 1965 
C6H18SiSn10.18 ± 0.26(CH3)3SnEILappert, Pedley, et al., 1971 
C6H18SiSn10.18 ± 0.26?EILappert, Simpson, et al., 1969 
C6H18Si29.8 ± 0.1C3H9SiPIPECOSzepes and Baer, 1984T = 0K
C6H18Si29.9(CH3)3SiEIPotzinger, Ritter, et al., 1975 
C6H18Si210.22 ± 0.18(CH3)3SiEILappert, Pedley, et al., 1971 
C6H18Si210.22 ± 0.18?EILappert, Simpson, et al., 1969 
C6H18Si210.0 ± 0.1?EIBand, Davidson, et al., Commun. 1967 
C6H18Si210.0 ± 0.1?EIConnor, Finney, et al., 1966 
C6H18Si210.69 ± 0.04?EIHess, Lampe, et al., 1964 
C7H18Si10.53 ± 0.09?EIHess, Lampe, et al., 1964 
C7H19NSi12.61 ± 0.03?EIHess, Lampe, et al., 1965 
C7H20Si210.1 ± 0.1?EIDavidson and Stephenson, 1967 
C8H9MnO5Si9.81 ± 0.11?EIHarris and Spalding, 1980 
C8H24O2Si315.8 ± 0.2?EIBorossay, Csakvari, et al., 1971 
C9H14SSi10.2 ± 0.1?EIDistefano, Ricci, et al., 1974 
C9H24O2Si315.4 ± 0.2?EIBorossay, Csakvari, et al., 1971 
C9H26O2Si315.3 ± 0.2?EIBorossay, Csakvari, et al., 1971 
C10H16Si10.1 ± 0.1?EIConnor, Finney, et al., 1966 
C11H20Si210.08 ± 0.09C6H5Si(CH3EIGaidis, Briggs, et al., 1971 
C16H22Si211.04 ± 0.03(C6H5)2SiCEIGaidis, Briggs, et al., 1971 
C16H22Si210.59 ± 0.03?EIGaidis, Briggs, et al., 1971 
C21H24Si210.83 ± 0.09(C6H5)3SiEIGaidis, Briggs, et al., 1971 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Szepes and Baer, 1984
Szepes, L.; Baer, T., Dissociation dynamics of energy selected hexamethyldisilane ions and the heats of formation of (CH3)3Si+ and (CH3)3Si, J. Am. Chem. Soc., 1984, 106, 273. [all data]

Szepes and Baer, 1984, 2
Szepes, L.; Baer, T., (CH3)3SiX tipusu vegyuletek vizsgalata fotoelectron-fotoion koincidenciaval,I. Meghatarozott belso energiaju hexametil-diszilan-ionok disszociaciojanak dinamikaja, Magy. Kem. Foly., 1984, 90, 104. [all data]

Band, Davidson, et al., Commun. 1967
Band, S.J.; Davidson, I.M.T.; Lambert, C.A.; Stephenson, I.L., Bond dissociation energies and heats of formation of trimethylsilyl compounds, Chem., Commun. 1967, 723. [all data]

Hess, Lampe, et al., 1965
Hess, G.G.; Lampe, F.W.; Sommer, L.H., An electron impact study of ionization and dissociation of trimethylsilanes, J. Am. Chem. Soc., 1965, 87, 5327. [all data]

Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J., Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen, Z. Naturforsch. A:, 1975, 30, 347. [all data]

Connor, Finney, et al., 1966
Connor, J.A.; Finney, G.; Leigh, G.J.; Haszeldine, R.N.; Robinson, P.J.; Sedgwick, R.D.; Simmons, R.F., Bond dissociation energies in organosilicon compounds, Chem. Commun., 1966, 178. [all data]

Hess, Lampe, et al., 1964
Hess, G.G.; Lampe, F.W.; Sommer, L.H., Bond dissociation energies and ion energetics in organosilicon compounds by electron impact, J. Am. Chem. Soc., 1964, 86, 3174. [all data]

Shin, Corderman, et al., 1990
Shin, S.K.; Corderman, R.R.; Beauchamp, J.L., Photoionization mass spectrometric studies of the methylsilanes Si(CH3)nH4-n (n = 0-3), Int. J. Mass Spectrom. Ion Processes, 1990, 101, 257. [all data]

Potzinger and Lampe, 1970
Potzinger, P.; Lampe, F.W., Thermochemistry of simple alkylsilanes, J. Phys. Chem., 1970, 74, 719. [all data]

Murphy and Beauchamp, 1977
Murphy, M.K.; Beauchamp, J.L., Photoionization mass spectrometry of the fluoromethylsilanes (CH3)n F4-nSi (n = 1-4), J. Am. Chem. Soc., 1977, 99, 2085. [all data]

MacLean and Sacher, 1974
MacLean, D.I.; Sacher, R.E., A study of some spectroscopic properties of Group IVA acetylides, J. Organomet. Chem., 1974, 74, 197. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Distefano, 1970
Distefano, G., Photoionization study of tetramethylsilicon, Inorg. Chem., 1970, 9, 1919. [all data]

Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals, J.Organometal. Chem., 1969, 17, PI. [all data]

Smolinsky and Vasile, 1973
Smolinsky, G.; Vasile, M.J., Mass spectra of vinyltrimethylsilane and vinyltri(methyl-d3)silane, Org. Mass Spectrom., 1973, 7, 1069. [all data]

Loguinov, Takhistov, et al., 1981
Loguinov, Y.; Takhistov, V.V.; Vatlina, L.P., Photoionization studies of substituted trimethylamines, Org. Mass Spectrom., 1981, 16, 239. [all data]

Akopyan, Vilesov, et al., 1975
Akopyan, M.E.; Vilesov, F.I.; Loginov, Y.V., Photoionization of amines and the monomolecular decomposition of excited molecular ions, Khim. Vys. Energ., 1975, 9, 327. [all data]

Borossay, Csakvari, et al., 1971
Borossay, J.; Csakvari, B.; Szepes, L., Determination of bond energies of organic silicon compounds on the basis of appearance potentials, Int. J. Mass Spectrom. Ion Phys., 1971, 7, 47. [all data]

Davidson and Stephenson, 1967
Davidson, I.M.T.; Stephenson, I.L., Appearance potentials of trialkylsilyl ions, J. Organometal. Chem., 1967, 7, 24. [all data]

Harris and Spalding, 1980
Harris, D.H.; Spalding, T.R., Electron impact study of compounds with main group IV element to transition metal bonds, Inorg. Chim. Acta, 1980, 39, 187. [all data]

Distefano, Ricci, et al., 1974
Distefano, G.; Ricci, A.; Danieli, R.; Foffani, A.; Innorta, G.; Torroni, S., Mass spectrometric evidence for p π-d π bonding between sulfur and the Group IVB elements, J. Organomet. Chem., 1974, 65, 205. [all data]

Gaidis, Briggs, et al., 1971
Gaidis, J.M.; Briggs, P.R.; Shannon, T.W., Mass spectra of disilanes. Phenyl-silicon interaction and silicon-silicon bond strength, J. Phys. Chem., 1971, 75, 974. [all data]


Notes

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