C3H5+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to C3H5+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
C3H5Br10.39BrPITraeger, 1984 
C3H5Br10.8 ± 0.1BrEIBurgers, Holmes, et al., 1983 
C3H5Cl11.04ClPITraeger, 1984 
C3H5Cl11.05 ± 0.04ClPIBuff, Parr, et al., 1981 
C3H5I10.30IEILossing and Holmes, 1984 
C3H5I9.80IPITraeger, 1984 
C3H5I9.9 ± 0.1IEIBurgers, Holmes, et al., 1983 
C3H611.86HPITraeger, 1984 
C3H611.90 ± 0.05HEISelim, 1980 
C3H611.78HPIButtrill, Williamson, et al., 1975 
C3H611.88 ± 0.03HPIKrassig, Reinke, et al., 1974 
C3H611.88HEILossing, 1971 
C3H611.43HPITraeger, 1984 
C3H611.47HPIButtrill, Williamson, et al., 1975 
C3H611.44 ± 0.05HPIKrassig, Reinke, et al., 1974 
C3H610.74 ± 0.09H(-)PIKrassig, Reinke, et al., 1974 
C3H611.49HEILossing, 1972 
C3H6BrNO11.15?EIDay, Gowenlock, et al., 1978 
C3H6ClNO11.75?EIDay, Gowenlock, et al., 1978 
C3H6N2O311.40?EIDay, Gowenlock, et al., 1978 
C3H6O11.8 ± 0.2OHEIGallegos and Kiser, 1962 
C3H6S10.66SHPITraeger, 1984, 2 
C3H6S11.5 ± 0.2SH?EIHobrock and Kiser, 1962 
C3H6S12.2 ± 0.2SH?EIGallegos and Kiser, 1962 
C3H6S210.8 ± 0.2S2HEIConde-Caprace and Collin, 1972 
C3H7Br11.86H2+BrPITraeger, 1980 
C3H7Br11.98H2+BrPITraeger, 1980 
C3H7Br12.23 ± 0.06H2+BrEIHolmes and Osborne, 1978 
C3H7Cl12.41H2+ClPITraeger, 1980 
C3H7Cl12.58H2+ClPITraeger, 1980 
C3H7I11.23H2+IPITraeger, 1980 
C3H7I11.34H2+BrPITraeger, 1980 
C3H7I11.67 ± 0.06H2+BrEIHolmes and Osborne, 1978 
C3H814. ± 1.H2+HPIAu, Cooper, et al., 1993 
C3H814.76H2+HEIOmura, 1961 
C3H8O12.6?PIRefaey and Chupka, 1968 
C4H5N12.70 ± 0.15CNEIKiser and Hobrock, 1962 
C4H6O11.1 ± 0.2CO+H?EIWada and Kiser, 1962 
C4H7Br12.6CH2BrEITomer, Turk, et al., 1972 
C4H7N13.18?EIHeerma and deRidder, 1970 
C4H811.36 ± 0.06CH3PIPECOVan der Meij, Van Eck, et al., 1989 
C4H811.20CH3PITraeger, 1984 
C4H811.8CH3EISenSharma and Franklin, 1973 
C4H811.28CH3EILossing, 1971 
C4H811.4 ± 0.1CH3EIBurgers and Holmes, 1982 
C4H811.33CH3PITraeger, 1984 
C4H811.8CH3EISenSharma and Franklin, 1973 
C4H811.45CH3EILossing, 1972 
C4H811.00CH3EILossing, 1972 
C4H811.25CH3PITraeger, 1984 
C4H811.33CH3EILossing, 1971 
C4H811.02CH3EILossing, 1972 
C4H810.9CH3EIMeisels and Giessner, 1971 
C4H811.30CH3PITraeger, 1984 
C4H8O13.72?EICollin and Conde-Caprace, 1966 
C4H8S12.7 ± 0.3?EIHobrock and Kiser, 1963 
C4H8S15.5 ± 0.2?EIGallegos and Kiser, 1962 
C4H1013.40?EIOmura, 1961 
C4H1014.55?EIOmura, 1961 
C4H10O11.6?EITsang and Harrison, 1970 
C4H10O12.0 ± 0.1CH3+H2OEIBurgers and Holmes, 1982 
C4H10OS12.4 ± 0.1?EIPotzinger, Stracke, et al., 1975 
C4H10S15.2 ± 0.2?EIHobrock and Kiser, 1963 
C4H10S12.41 ± 0.05CH3SH+HPIAkopyan, Sergeev, et al., 1970 
C4H10S14.8 ± 0.2?EIHobrock and Kiser, 1962, 2 
C5H814.20 ± 0.02?EIFranklin and Mogenis, 1967 
C5H814.04 ± 0.10C2H2+HEIPuttemans and Delvaux, 1973 
C5H9Br12.2?EITomer, Turk, et al., 1972 
C5H9N13.73?EIHeerma, deRidder, et al., 1969 
C5H9N13.35?EIHeerma and deRidder, 1970 
C5H9N13.50?EIHeerma and deRidder, 1970 
C5H10O~12.8?EICollin and Conde-Caprace, 1966 
C5H11F14.12?EILorquet-Julien, 1961 
C5H11N9.55C2H6NPIAkopyan, Vilesov, et al., 1975 
C5H1213.13?EILampe and Field, 1959 
C6H1013.68 ± 0.05?EIPraet, 1970 
C6H1012.12 ± 0.12?EIWinters and Collins, 1969 
C6H1012.28 ± 0.17?EIWinters and Collins, 1969 
C6H1010.2C3H5EIShikhmamedbekova, Aslanov, et al., 1970 
C6H1014.05 ± 0.05C3H5EIPraet, 1970 
C6H1012.03 ± 0.13?EIWinters and Collins, 1969 
C6H1011.65 ± 0.14?EIWinters and Collins, 1969 
C6H1010.64 ± 0.14?EIWinters and Collins, 1969 
C6H10>10.9?EIHart and Friedli, 1970 
C6H1013.06 ± 0.02?EIFranklin and Mogenis, 1967 
C6H1014.09 ± 0.05?EIPraet, 1970 
C6H1013.7C4H7EIShikhmamedbekova, Aslanov, et al., 1970 
C6H1014.9 ± 0.1?EIPraet, 1970 
C6H1012.45 ± 0.13?EIWinters and Collins, 1969 
C6H1013.9 ± 0.01?EIPraet, 1970 
C6H11Br12.52 ± 0.05?PISergeev, Akopyan, et al., 1973 
C6H1213.20 ± 0.08C3H7EIRabbih, Selim, et al., 1981 
C6H15P16.4 ± 0.3?EIBogolyubov, Grishin, et al., 1969 
C7H1213.25 ± 0.11?EIWinters and Collins, 1968 
C7H1213.22 ± 0.12?EIWinters and Collins, 1968 
C7H1211.90 ± 0.10?EIWinters and Collins, 1968 
C7H1213.38 ± 0.11?EIWinters and Collins, 1968 
C7H1213.29 ± 0.11?EIWinters and Collins, 1968 
C7H1213.46 ± 0.09?EIWinters and Collins, 1968 
C7H1612.7 ± 0.1?PIBrehm, 1966 
C8H10N2.9 ± 0.35C5H5NCADKatritzky, Watson, et al., 1990 
C8H12N4O210.85?EIDay, Gowenlock, et al., 1978 
C8H1414.27 ± 0.03?EIFranklin and Mogenis, 1967 
C10H1815.0?EIPolyakova, Zimina, et al., 1960 
C10H18N2O611.80?EIDay, Gowenlock, et al., 1978 
C12H22N2O412.95?EIDay, Gowenlock, et al., 1978 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Traeger, 1984
Traeger, J.C., A study of the allyl cation thermochemistry by photoionization mass spectrometry, Int. J. Mass Spectrom. Ion Processes, 1984, 58, 259. [all data]

Burgers, Holmes, et al., 1983
Burgers, P.C.; Holmes, J.L.; Mommers, A.A.; Szulejko, J.E., The collisionally induced dissociation of allyl and 2-propenyl cations, Org. Mass Spectrom., 1983, 18, 596. [all data]

Buff, Parr, et al., 1981
Buff, R.D.; Parr, A.C.; Jason, A.J., The photoionization of allyl chloride from onset to 20 eV, Int. J. Mass Spectrom. Ion Phys., 1981, 40, 31. [all data]

Lossing and Holmes, 1984
Lossing, F.P.; Holmes, J.L., Stabilization energy and ion size in carbocations in the gas phase, J. Am. Chem. Soc., 1984, 106, 6917. [all data]

Selim, 1980
Selim, E.T.M., Ionization dissociation of propylene by electron impact, Indian J. Pure Appl. Phys., 1980, 18, 31. [all data]

Buttrill, Williamson, et al., 1975
Buttrill, S.E., Jr.; Williamson, A.D.; LeBreton, P., Photoionization measurement of the heat of formation of allyl cations, J. Chem. Phys., 1975, 62, 1586. [all data]

Krassig, Reinke, et al., 1974
Krassig, R.; Reinke, D.; Baumgartel, H., Photo-reaktionen kleiner organischer molekule II. Die photoionenspektren der Isomeren propylen-cyclopropan und acetaldehyd-athylenoxyd, Ber. Bunsen-Ges. Phys. Chem., 1974, 78, 425. [all data]

Lossing, 1971
Lossing, F.P., Free radicals by mass spectrometry. XLIII. Ionization potentials and ionic heats of formation for vinyl, allyl, and benzyl radicals, Can. J. Chem., 1971, 49, 357. [all data]

Lossing, 1972
Lossing, F.P., Free radicals by mass spectrometry. XLV. Ionization potentials and heats of formation of C3H3, C3H5, and C4H7 radicals and ions, Can. J. Chem., 1972, 50, 3973. [all data]

Day, Gowenlock, et al., 1978
Day, J.S.; Gowenlock, B.G.; Johnson, C.A.F.; McInally, I.D.; Pfab, J., Appearance potential studies of some geminal substituted C-nitroso- compounds, J. Chem. Soc. Perkin Trans. 2, 1978, 10, 1110. [all data]

Gallegos and Kiser, 1962
Gallegos, E.J.; Kiser, R.W., Electron impact spectroscopy of the four- and five-membered, saturated heterocyclic compounds containing nitrogen, oxygen and sulfur, J. Phys. Chem., 1962, 66, 136. [all data]

Traeger, 1984, 2
Traeger, J.C., Heat of formation for the SH radical by photoionization mass spectrometry, Org. Mass Spectrom., 1984, 19, 514. [all data]

Hobrock and Kiser, 1962
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of propylene sulfide, J. Phys. Chem., 1962, 66, 1551. [all data]

Conde-Caprace and Collin, 1972
Conde-Caprace, G.; Collin, J.E., Ionization and dissociation of cyclic ethers thioethers by electron-impact. A comparison between 1,3-dioxolane, 1,3-dithiolane and 1,3-oxathiolane, Org. Mass Spectrom., 1972, 6, 415. [all data]

Traeger, 1980
Traeger, J.C., Photoionization mass spectrometry of the propyl halides, Int. J. Mass Spectrom. Ion Phys., 1980, 32, 309. [all data]

Holmes and Osborne, 1978
Holmes, J.L.; Osborne, A.D., Energy partitioning in the metastable fragmentation [C3H7]+ → [C3H5]+ + H2, Org. Mass Spectrom., 1978, 13, 133. [all data]

Au, Cooper, et al., 1993
Au, J.W.; Cooper, G.; Brion, C.E., The molecular and dissociative photoionization of ethane, propane, and n-butane: Absolute oscillator strengths (10-80 eV) and breakdown pathways, Chem. Phys., 1993, 173, 241. [all data]

Omura, 1961
Omura, I., Mass spectra at low ionizing voltage and bond dissociation energies of molecular ions from hydrocarbons, Bull. Chem. Soc. Japan, 1961, 34, 1227. [all data]

Refaey and Chupka, 1968
Refaey, K.M.A.; Chupka, W.A., Photoionization of the lower aliphatic alcohols with mass analysis, J. Chem. Phys., 1968, 48, 5205. [all data]

Kiser and Hobrock, 1962
Kiser, R.W.; Hobrock, B.G., The ionization potentials of cyclopropyl radical and cyclopropyl cyanide, J. Phys. Chem., 1962, 66, 957. [all data]

Wada and Kiser, 1962
Wada, Y.; Kiser, R.W., Electron impact spectroscopy of some substituted oxiranes, J. Phys. Chem., 1962, 66, 1652. [all data]

Tomer, Turk, et al., 1972
Tomer, K.B.; Turk, J.; Shapiro, R.H., Anchimeric assistance in electron-impact reactions: Homoallylic systems, Org. Mass Spectrom., 1972, 6, 235. [all data]

Heerma and deRidder, 1970
Heerma, W.; deRidder, J.J., The electron-impact induced fragmentation of some alkyl isocyanides and alpha-branched alkyl cyanides, Org. Mass Spectrom., 1970, 3, 1439. [all data]

Van der Meij, Van Eck, et al., 1989
Van der Meij, C.E.; Van Eck, J.; Niehaus, A., The decomposition of C4H8 complexes at controlled internal energies, Chem. Phys., 1989, 130, 325. [all data]

SenSharma and Franklin, 1973
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Burgers and Holmes, 1982
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Meisels and Giessner, 1971
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Collin and Conde-Caprace, 1966
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Hobrock and Kiser, 1963
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Akopyan, Sergeev, et al., 1970
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Brehm, B., Massenspektrometrische Untersuchung der Photoionisation von Molekulen, Z. Naturforsch., 1966, 21a, 196. [all data]

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Notes

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