As+ (structure unspecified)
- Formula: As+
- Molecular weight: 74.92105
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to As+ (ion structure unspecified)
| Precursor | AP (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| AsCl3 | 17.4 ± 0.1 | ? | EI | Ozgen, 1983 | |
| AsCl3 | 20.4 ± 0.4 | 3Cl | EI | Pabst, Sharpe, et al., 1980 | |
| AsF3 | 27.0 ± 0.4 | 3F | EI | Pabst, Sharpe, et al., 1980 | |
| H3As | 15.0 ± 0.3 | H2+H | EI | Saalfeld and McDowell, 1967 | |
| H3As | 14.8 ± 0.2 | H2+H | EI | Saalfeld and Svec, 1963 | |
| As2 | 13.9 ± 0.3 | As | EI | Hirayama, Straw, et al., 1985 | |
| As2 | 13.9 ± 0.4 | As | EI | DeMaria, Malaspina, et al., 1970 | |
| H4As2 | 14.3 ± 0.3 | ? | EI | Saalfeld and Svec, 1963, 2 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ozgen, 1983
Ozgen, T.,
Mass spectrometric determination of the appearance potentials of PCl3, AsCl3, SbCl3, BiCl3 and their fragments,
Int. J. Mass Spectrom. Ion Processes, 1983, 48, 427. [all data]
Pabst, Sharpe, et al., 1980
Pabst, R.E.; Sharpe, M.C.; Margrave, J.L.; Franklin, J.L.,
An electron impact study of the appearance energies of positive ions from AsF3, AsCl3, AsBr3 and AsF5,
Int. J. Mass Spectrom. Ion Phys., 1980, 33, 187. [all data]
Saalfeld and McDowell, 1967
Saalfeld, F.E.; McDowell, M.V.,
The mass spectra of volatile hydrides. V. Silylarsine,
Inorg. Chem., 1967, 6, 96. [all data]
Saalfeld and Svec, 1963
Saalfeld, F.E.; Svec, H.J.,
The mass spectra of volatile hydrides. I. The monoelemental hydrides of the group IVB and VB elements,
Inorg. Chem., 1963, 2, 46. [all data]
Hirayama, Straw, et al., 1985
Hirayama, C.; Straw, R.D.; Hobgood, H.M.,
Equilibria over gas in the Knudsen cell range,
J. Less-Common Met., 1985, 109, 331. [all data]
DeMaria, Malaspina, et al., 1970
DeMaria, G.; Malaspina, L.; Piacente, V.,
Mass spectrometric study of the GaAs system,
J. Chem. Phys., 1970, 52, 1019. [all data]
Saalfeld and Svec, 1963, 2
Saalfeld, F.E.; Svec, H.J.,
The mass spectra of volatile hydrides. II. Some higher hydrides of the group IVB and VB elements,
Inorg. Chem., 1963, 2, 50. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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