Digermane, hexamethyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C6H18Ge2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.09PETraven', Redchenko, et al., 1982LBLHLM
8.1PESzepes, Koranyi, et al., 1981LLK
8.18 ± 0.11EILappert, Pedley, et al., 1971LLK
8.60PEMochida, Worley, et al., 1985Vertical value; LBLHLM
8.59PETraven', Redchenko, et al., 1982Vertical value; LBLHLM
8.6 ± 0.05PESzepes, Koranyi, et al., 1981Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H9Ge+9.96 ± 0.16(CH3)3GeEILappert, Pedley, et al., 1971LLK
C3H9Ge+11.3 ± 0.2?EIdeRidder and Dijkstra, 1968RDSH
C5H15Ge2+10.8 ± 0.2CH3EIdeRidder and Dijkstra, 1968RDSH
C6H18Ge2+7.76 ± 0.01?EIPitt, Bursey, et al., 1970RDSH
C6H18Ge2+8.5 ± 0.2?EIdeRidder and Dijkstra, 1968RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin A.A.Kutin, Moscow, Russia
NIST MS number 301885

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References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Traven', Redchenko, et al., 1982
Traven', V.F.; Redchenko, V.V.; Bartenev, Y.; Stepanov, B.I., Photoelectron spectra of permethyl-di-, -tri-, and -tetra-germanes, J. Gen. Chem. USSR, 1982, 52, 310, In original 358. [all data]

Szepes, Koranyi, et al., 1981
Szepes, L.; Koranyi, T.; Naray-Szabo, G.; Modelli, A.; Distefano, G., Ultraviolet photoelectron spectra of group IV hexamethyl derivatives containing a metal-metal bond, J. Organomet. Chem., 1981, 217, 35. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Mochida, Worley, et al., 1985
Mochida, K.; Worley, S.; Kochi, J., UV photoelectron spectra of peralkylated catenates of Group 4B elements (silicon, germanium, and tin), Bull. Chem. Soc. Jpn., 1985, 58, 3389. [all data]

deRidder and Dijkstra, 1968
deRidder, J.J.; Dijkstra, G., On the mass spectra of some alkyl digermanium compounds, Org. Mass Spectrom., 1968, 1, 647. [all data]

Pitt, Bursey, et al., 1970
Pitt, C.G.; Bursey, M.M.; Rogerson, P.F., Catenates of the group IV elements. Correlation of σ electron energies, J. Am. Chem. Soc., 1970, 92, 519. [all data]


Notes

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