Phenyl trichlorosilane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid314.7J/mol*KN/AGumbatov and Kostrykov, 1965 

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
220.7298.15Gumbatov and Kostrykov, 1965T = 14 to 289 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil474.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Ttriple233.4KN/AGumbatov and Kostryukov, 1965Uncertainty assigned by TRC = 0.2 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
51.1348.N/ASokolov, Karapet'yants, et al., 1970Based on data from 333. to 453. K.; AC
47.9390.IJenkins and Chambers, 1954Based on data from 375. to 470. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference
374.8 to 470.64.10831641.-74.Jenkins and Chambers, 1954

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
11.660233.4Gumbatov and Kostrykov, 1965Smoothed table gives H = 11650 J/mol.; DH
11.66233.4Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
49.96233.4Gumbatov and Kostrykov, 1965Smoothed; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference
9.1PEVeszpremi, Harada, et al., 1984
9.55PEVeszpremi, Harada, et al., 1984

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gumbatov and Kostrykov, 1965
Gumbatov, D.O.; Kostrykov, V.N., Thermodynamic studies at low temperatures. The specific heat, entropy, enthalpy, and internal rotation potential of C6H5SiCl3, Zhur. Fiz. Khim., 1965, 39, 116-122. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Gumbatov and Kostryukov, 1965
Gumbatov, D.O.; Kostryukov, V.N., Thermodynamic studies at low temperatures. The specific heat, entropy, enthalpy, and internal rotation potential of C6H5SiCl3, Zh. Fiz. Khim., 1965, 39, 116-22. [all data]

Sokolov, Karapet'yants, et al., 1970
Sokolov, V.B.; Karapet'yants, M.Kh.; Goncharov, A.K., Tr. Mosk. Khim. Tekhnol. Inst., 1970, 67, 37. [all data]

Jenkins and Chambers, 1954
Jenkins, Arthur C.; Chambers, George F., Vapor Pressures of Silicon Compounds, Ind. Eng. Chem., 1954, 46, 11, 2367-2369, https://doi.org/10.1021/ie50539a043 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Veszpremi, Harada, et al., 1984
Veszpremi, T.; Harada, Y.; Ohno, K.; Mutoh, H., Jr., Photoelectron and penning electron spectroscopic investigation of phenylhalosilanes, J. Organomet. Chem., 1984, 266, 9. [all data]


Notes

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