Borane, triethyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar330.05J/mol*KN/AKostryukov, Samorukov, et al., 1977 
solid,1 bar338.1J/mol*KN/AFurukawa, 1955Below 15°. Debye extrapolation.

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
240.298.15Kostryukov, Samorukov, et al., 1977T = 12 to 322 K. Data calculated from equation. Cp = 6.2328 + 0.17161 T cal/mol*K.
241.4300.Furukawa, 1955T = 15 to 300 K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.6PEHolliday, Reade, et al., 1971LLK
9.7 ± 0.1EILappert, Pedley, et al., 1966RDSH
9.0 ± 0.2EILaw and Margrave, 1956RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
B+30.1 ± 0.5?EILaw and Margrave, 1956RDSH
C4H10B+9.6 ± 0.2C2H5EILaw and Margrave, 1956RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kostryukov, Samorukov, et al., 1977
Kostryukov, V.N.; Samorukov, O.P.; Samorukova, N.Kh.; Krasavin, A.M.; Petrunin, A.B., Heat capacity of triethylboron at low temperature, Vses. Konf. Kalorim. [Russhir. Tezisy Dokl.] 7th, 1977, 2, 387-390. [all data]

Furukawa, 1955
Furukawa, G.T., Heat capacity, heats of fusion and vaporization, and vapor pressure of triethylborane, (C2H5)3B, NBS Report, 1955, No. 3712, 1-16. [all data]

Holliday, Reade, et al., 1971
Holliday, A.K.; Reade, W.; Johnstone, R.A.W.; Neville, A.F., Photo-electron spectrum of trivinylboron, Chem. Commun., 1971, 51. [all data]

Lappert, Pedley, et al., 1966
Lappert, M.F.; Pedley, J.B.; Riley, P.N.K.; Tweedale, A., Ionisation potentials and electronic spectra of halogeno- and amino-boranes, and a study of some redistribution reactions, Chem. Commun., 1966, 788. [all data]

Law and Margrave, 1956
Law, R.W.; Margrave, J.L., Mass spectrometer appearance potentials for positive ion fragments from BF3, B(CH3)3, B(C2H5)3, B(OCH3)3, and HB(OCH3)2, J. Chem. Phys., 1956, 25, 1086. [all data]


Notes

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