ClSCN+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 57280 ± 560 gas Frost, MacDonald, et al., 1981

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 40260 ± 320 gas Frost, MacDonald, et al., 1981

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 32440 ± 320 gas Frost, MacDonald, et al., 1981

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 25900 ± 320 gas Frost, MacDonald, et al., 1981

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 22830 ± 320 gas Frost, MacDonald, et al., 1981

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 20980 ± 320 gas Frost, MacDonald, et al., 1981

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 17910 ± 320 gas Frost, MacDonald, et al., 1981
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 680 ± 40 gas PE Leung, Suffolk, et al., 1986
SCl stretch 570 ± 50 gas PE Frost, MacDonald, et al., 1981

Additional references: Jacox, 1994, page 194

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, MacDonald, et al., 1981
Frost, D.C.; MacDonald, C.B.; McDowell, C.A.; Westwood, N.P.C., Preparation and HeI photoelectron spectra of the halogen thiocyanates, XSCN (X = Cl and Br), J. Am. Chem. Soc., 1981, 103, 4423. [all data]

Leung, Suffolk, et al., 1986
Leung, H.; Suffolk, R.J.; Watts, J.D., A photoelectron spectroscopic and theoretical study of the halogen and hydrogen thiocyanates and isothiocyanates, Chem. Phys., 1986, 109, 289. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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