Borane, triphenyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub22.0 ± 0.60kcal/molN/ASteele, 1978 

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
15.4438.AStephenson and Malanowski, 1987Based on data from 423. to 568. K.
15.4 ± 0.50486.N/AFinch, Gardner, et al., 1967Based on data from 423. to 548. K.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference
24.81 ± 0.60360.TE,MEGovorchin, Kana'an, et al., 1984

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.60 ± 0.03PIRodionov, Potapov, et al., 1973LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
BC12H10+10.2C6H5PIRodionov, Potapov, et al., 1973LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, 1978
Steele, W.V., The standard enthalpies of formation of the triphenyl compounds of the Group V elements. 1. Triphenylamine and the Ph-N bond-dissociation energy, J. Chem. Thermodyn., 1978, 10, 441-444. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Finch, Gardner, et al., 1967
Finch, Arthur; Gardner, P.J.; Watts, G.B., Thermochemistry of the trialkylthioboranes and triphenylthioborane, Trans. Faraday Soc., 1967, 63, 1603, https://doi.org/10.1039/tf9676301603 . [all data]

Govorchin, Kana'an, et al., 1984
Govorchin, Steven W.; Kana'an, Adli S.; Kanamueller, Joseph M., Sublimation study of triphenyl boron and the bond-dissociation enthalpy of B«58872»C6H5, The Journal of Chemical Thermodynamics, 1984, 16, 8, 703-709, https://doi.org/10.1016/0021-9614(84)90053-3 . [all data]

Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L., Photoionization of certain aromatic heteroorganic compounds, High Energy Chem., 1973, 7, 249, In original 278. [all data]


Notes

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